2026
|
Ji, Zekai; Jayakumar, Sanjeevi; Limpo, Carlos Maria Alava; Madhav, Aravind; Trubyanov, Maxim; Zhang, Pengxiang; V, Daria Andreeva; Lee, Jong Hak; Ozyilmaz, Barbaros 3D interconnected pore networks enable superior volumetric CO2
uptake in amine-functionalized nanoporous carbon for direct air
capture CARBON CAPTURE SCIENCE & TECHNOLOGY, 19 , 2026, DOI: 10.1016/j.ccst.2026.100600. Abstract | BibTeX | Endnote @article{WOS:001724390300001,
title = {3D interconnected pore networks enable superior volumetric CO2
uptake in amine-functionalized nanoporous carbon for direct air
capture},
author = {Zekai Ji and Sanjeevi Jayakumar and Carlos Maria Alava Limpo and Aravind Madhav and Maxim Trubyanov and Pengxiang Zhang and Daria Andreeva V and Jong Hak Lee and Barbaros Ozyilmaz},
doi = {10.1016/j.ccst.2026.100600},
times_cited = {0},
issn = {2772-6568},
year = {2026},
date = {2026-06-01},
journal = {CARBON CAPTURE SCIENCE & TECHNOLOGY},
volume = {19},
publisher = {ELSEVIER},
address = {RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS},
abstract = {Direct Air Capture (DAC) is a critical technology for mitigating
atmospheric CO2 concentrations, but current systems require substantial
space and high energy input, largely due to the low volumetric CO2
capture capacity of existing sorbents. A major limitation arises from
the intrinsic trade-off in conventional mesoporous platforms, where
increasing amine loading often compromises CO2 diffusion efficiency,
resulting in poor volumetric performance. In this report, we introduce a
solid-state sorbent platform that overcomes this limitation by
leveraging a fully interconnected three-dimensional (3D) pore network.
The sorbent, composed of polyethyleneimine (PEI)-functionalized
nanoporous amorphous carbon (NAC) millimeter-sized monoliths, features a
hierarchically organized pore architecture with high volumetric pore
density, enabling deep and uniform amine infiltration while maintaining
unobstructed CO2 diffusion pathways. This synergistic pore design yields
a remarkable volumetric CO2 uptake of similar to 1.6 mmol/cm & sup3;
under pre-hydrated conditions-over threefold higher than that of the
best-performing shaped sorbents reported to date. The NAC-PEI monoliths
further exhibit cyclic stability, mechanical robustness, and negligible
pressure drop, supporting their integration into compact and
energy-efficient continuous DAC modules. These findings establish pore
interconnectivity as a key design principle for next-generation solid
sorbents, enabling space-efficient, high-performance carbon removal
systems suitable for urban and distributed deployment.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Direct Air Capture (DAC) is a critical technology for mitigating
atmospheric CO2 concentrations, but current systems require substantial
space and high energy input, largely due to the low volumetric CO2
capture capacity of existing sorbents. A major limitation arises from
the intrinsic trade-off in conventional mesoporous platforms, where
increasing amine loading often compromises CO2 diffusion efficiency,
resulting in poor volumetric performance. In this report, we introduce a
solid-state sorbent platform that overcomes this limitation by
leveraging a fully interconnected three-dimensional (3D) pore network.
The sorbent, composed of polyethyleneimine (PEI)-functionalized
nanoporous amorphous carbon (NAC) millimeter-sized monoliths, features a
hierarchically organized pore architecture with high volumetric pore
density, enabling deep and uniform amine infiltration while maintaining
unobstructed CO2 diffusion pathways. This synergistic pore design yields
a remarkable volumetric CO2 uptake of similar to 1.6 mmol/cm & sup3;
under pre-hydrated conditions-over threefold higher than that of the
best-performing shaped sorbents reported to date. The NAC-PEI monoliths
further exhibit cyclic stability, mechanical robustness, and negligible
pressure drop, supporting their integration into compact and
energy-efficient continuous DAC modules. These findings establish pore
interconnectivity as a key design principle for next-generation solid
sorbents, enabling space-efficient, high-performance carbon removal
systems suitable for urban and distributed deployment. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFZekai Ji
Sanjeevi Jayakumar
Carlos Maria Alava Limpo
Aravind Madhav
Maxim Trubyanov
Pengxiang Zhang
Daria Andreeva V
Jong Hak Lee
Barbaros Ozyilmaz
- TI3D interconnected pore networks enable superior volumetric CO2
uptake in amine-functionalized nanoporous carbon for direct air
capture - SOCARBON CAPTURE SCIENCE & TECHNOLOGY
- DTArticle
- ABDirect Air Capture (DAC) is a critical technology for mitigating
atmospheric CO2 concentrations, but current systems require substantial
space and high energy input, largely due to the low volumetric CO2
capture capacity of existing sorbents. A major limitation arises from
the intrinsic trade-off in conventional mesoporous platforms, where
increasing amine loading often compromises CO2 diffusion efficiency,
resulting in poor volumetric performance. In this report, we introduce a
solid-state sorbent platform that overcomes this limitation by
leveraging a fully interconnected three-dimensional (3D) pore network.
The sorbent, composed of polyethyleneimine (PEI)-functionalized
nanoporous amorphous carbon (NAC) millimeter-sized monoliths, features a
hierarchically organized pore architecture with high volumetric pore
density, enabling deep and uniform amine infiltration while maintaining
unobstructed CO2 diffusion pathways. This synergistic pore design yields
a remarkable volumetric CO2 uptake of similar to 1.6 mmol/cm & sup3;
under pre-hydrated conditions-over threefold higher than that of the
best-performing shaped sorbents reported to date. The NAC-PEI monoliths
further exhibit cyclic stability, mechanical robustness, and negligible
pressure drop, supporting their integration into compact and
energy-efficient continuous DAC modules. These findings establish pore
interconnectivity as a key design principle for next-generation solid
sorbents, enabling space-efficient, high-performance carbon removal
systems suitable for urban and distributed deployment. - Z90
- PUELSEVIER
- PARADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS
- SN2772-6568
- VL19
- DI10.1016/j.ccst.2026.100600
- UTWOS:001724390300001
- ER
- EF
|
Zhang, Hongji; Grebenko, Artem K; Litvinov, Dmitrii; Zheng, Wenwen; Iakoubovskii, Konstantin V; Grebenchuk, Sergey Y; Makarova, Anna; Fedorov, Alexander; Starkov, Andrei; Orofeo, Carlo M; Vyalikh, Denis V; Lanza, Mario; Koperski, Maciej; Novoselov, Kostya S; Toh, Chee-tat; Ozyilmaz, Barbaros Breaking the 2-nm Barrier in Hard Disk Drives Using Monolayer Amorphous
Carbon Overcoats ADVANCED MATERIALS, 38 (15), 2026, DOI: 10.1002/adma.202519149. Abstract | BibTeX | Endnote @article{WOS:001680918000001,
title = {Breaking the 2-nm Barrier in Hard Disk Drives Using Monolayer Amorphous
Carbon Overcoats},
author = {Hongji Zhang and Artem K Grebenko and Dmitrii Litvinov and Wenwen Zheng and Konstantin V Iakoubovskii and Sergey Y Grebenchuk and Anna Makarova and Alexander Fedorov and Andrei Starkov and Carlo M Orofeo and Denis V Vyalikh and Mario Lanza and Maciej Koperski and Kostya S Novoselov and Chee-tat Toh and Barbaros Ozyilmaz},
doi = {10.1002/adma.202519149},
times_cited = {0},
issn = {0935-9648},
year = {2026},
date = {2026-03-01},
journal = {ADVANCED MATERIALS},
volume = {38},
number = {15},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {The rapid growth of artificial intelligence (AI) has increased the
demand for large-scale data storage, making hard disk drives (HDDs)
indispensable in data centers due to their cost-effectiveness and
stability. To support AI-driven data requirements, increasing the areal
storage density is critical. However, this metric is increasingly
constrained by the carbon overcoat (COC), the essential protective layer
for magnetic media. Traditional diamond-like carbon (DLC) can no longer
fulfill the stringent demands for ultrathin coatings and high thermal
stability required by next-generation technologies like Heat-Assisted
Magnetic Recording (HAMR) and bit-patterned media. Here, we introduce
monolayer amorphous carbon (MAC) as a superior alternative. MAC is
directly grown on the heterogeneous (Fe, Pt, SiO2) HDD surface at low
temperatures (similar to 300 degrees C), achieving an uniform 0.8 nm
thickness across 2.5-inch disks. Despite its atomic thickness, MAC
demonstrates high corrosion resistance and low roughness comparable to
commercial 2.5 nm COCs. Its fully amorphous, sp2-hybridized structure
ensures excellent thermal stability under HAMR-like conditions (similar
to 450 degrees C) and a low friction coefficient, enabling potential
lubricant-free operation. Replacing traditional COCs with MAC
facilitates the development of HDD media capable of achieving 10 Tb/in2,
addressing the urgent storage demands of the digital era.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The rapid growth of artificial intelligence (AI) has increased the
demand for large-scale data storage, making hard disk drives (HDDs)
indispensable in data centers due to their cost-effectiveness and
stability. To support AI-driven data requirements, increasing the areal
storage density is critical. However, this metric is increasingly
constrained by the carbon overcoat (COC), the essential protective layer
for magnetic media. Traditional diamond-like carbon (DLC) can no longer
fulfill the stringent demands for ultrathin coatings and high thermal
stability required by next-generation technologies like Heat-Assisted
Magnetic Recording (HAMR) and bit-patterned media. Here, we introduce
monolayer amorphous carbon (MAC) as a superior alternative. MAC is
directly grown on the heterogeneous (Fe, Pt, SiO2) HDD surface at low
temperatures (similar to 300 degrees C), achieving an uniform 0.8 nm
thickness across 2.5-inch disks. Despite its atomic thickness, MAC
demonstrates high corrosion resistance and low roughness comparable to
commercial 2.5 nm COCs. Its fully amorphous, sp2-hybridized structure
ensures excellent thermal stability under HAMR-like conditions (similar
to 450 degrees C) and a low friction coefficient, enabling potential
lubricant-free operation. Replacing traditional COCs with MAC
facilitates the development of HDD media capable of achieving 10 Tb/in2,
addressing the urgent storage demands of the digital era. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFHongji Zhang
Artem K Grebenko
Dmitrii Litvinov
Wenwen Zheng
Konstantin V Iakoubovskii
Sergey Y Grebenchuk
Anna Makarova
Alexander Fedorov
Andrei Starkov
Carlo M Orofeo
Denis V Vyalikh
Mario Lanza
Maciej Koperski
Kostya S Novoselov
Chee-tat Toh
Barbaros Ozyilmaz
- TIBreaking the 2-nm Barrier in Hard Disk Drives Using Monolayer Amorphous
Carbon Overcoats - SOADVANCED MATERIALS
- DTArticle
- ABThe rapid growth of artificial intelligence (AI) has increased the
demand for large-scale data storage, making hard disk drives (HDDs)
indispensable in data centers due to their cost-effectiveness and
stability. To support AI-driven data requirements, increasing the areal
storage density is critical. However, this metric is increasingly
constrained by the carbon overcoat (COC), the essential protective layer
for magnetic media. Traditional diamond-like carbon (DLC) can no longer
fulfill the stringent demands for ultrathin coatings and high thermal
stability required by next-generation technologies like Heat-Assisted
Magnetic Recording (HAMR) and bit-patterned media. Here, we introduce
monolayer amorphous carbon (MAC) as a superior alternative. MAC is
directly grown on the heterogeneous (Fe, Pt, SiO2) HDD surface at low
temperatures (similar to 300 degrees C), achieving an uniform 0.8 nm
thickness across 2.5-inch disks. Despite its atomic thickness, MAC
demonstrates high corrosion resistance and low roughness comparable to
commercial 2.5 nm COCs. Its fully amorphous, sp2-hybridized structure
ensures excellent thermal stability under HAMR-like conditions (similar
to 450 degrees C) and a low friction coefficient, enabling potential
lubricant-free operation. Replacing traditional COCs with MAC
facilitates the development of HDD media capable of achieving 10 Tb/in2,
addressing the urgent storage demands of the digital era. - Z90
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- SN0935-9648
- VL38
- DI10.1002/adma.202519149
- UTWOS:001680918000001
- ER
- EF
|
Tewari, Chetna; Rawat, Kundan Singh; Kim, Youngnam; Arya, Tanuja; Dhali, Sunil; Rana, Sravendra; Andreeva, Daria V; Ozyilmaz, Barbaros; Mahfouz, Remi; Qari, Nada; Jung, Yong Chae; Sahoo, Nanda Gopal; Novoselov, Kostya S Functional nanocarbons from waste plastics for energy storage
applications RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 226 (E), 2026, DOI: 10.1016/j.rser.2025.116443. Abstract | BibTeX | Endnote @article{WOS:001614303300001,
title = {Functional nanocarbons from waste plastics for energy storage
applications},
author = {Chetna Tewari and Kundan Singh Rawat and Youngnam Kim and Tanuja Arya and Sunil Dhali and Sravendra Rana and Daria V Andreeva and Barbaros Ozyilmaz and Remi Mahfouz and Nada Qari and Yong Chae Jung and Nanda Gopal Sahoo and Kostya S Novoselov},
doi = {10.1016/j.rser.2025.116443},
times_cited = {4},
issn = {1364-0321},
year = {2026},
date = {2026-01-01},
journal = {RENEWABLE & SUSTAINABLE ENERGY REVIEWS},
volume = {226},
number = {E},
publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
abstract = {The mismanagement of waste plastic could lead to significant
environmental challenge, underscoring the urgent need for adopting
innovative strategies that will address its management and utilization.
At the same time, the growing demand for sustainable energy storage
materials necessitates the exploration of resourceful solutions
including advanced plastic-based materials. Addressing these dual
concerns, this review examines the transformation of waste plastics into
functional nanocarbons (FNCs) for energy-related applications. This
review provides a comprehensive analysis of zero-to-three-dimensional
FNCs derived from waste plastics, detailing synthesis techniques such as
chemical vapor deposition, pyrolysis/catalytic pyrolysis, and
hydrothermal carbonization, along with the underlying mechanisms. Key
factors influencing the conversion process-including pressure,
temperature, and catalytic systems-are thoroughly examined. Discussions
on morphology and surface chemistry shed light on strategies to optimize
material properties for specific applications. Special attention is
given to the performance of FNCs in supercapacitors and batteries, using
benchmarks such as electrical conductivity, specific surface area, and
cycling stability to evaluate their suitability for energy storage.
Additionally, the review incorporates a circular economic perspective,
offering insights into how upcycling waste plastics into FNCs can
contribute to a more sustainable future. It identifies critical research
gaps, evaluates the environmental impacts of these processes, and
highlights promising opportunities for innovation. By fostering
interdisciplinary collaboration and bridging knowledge gaps, this review
aims to inspire advancements in both waste plastic upcycling and energy
technologies, ultimately contributing to sustainable solutions for
urgent environmental and energy challenges.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The mismanagement of waste plastic could lead to significant
environmental challenge, underscoring the urgent need for adopting
innovative strategies that will address its management and utilization.
At the same time, the growing demand for sustainable energy storage
materials necessitates the exploration of resourceful solutions
including advanced plastic-based materials. Addressing these dual
concerns, this review examines the transformation of waste plastics into
functional nanocarbons (FNCs) for energy-related applications. This
review provides a comprehensive analysis of zero-to-three-dimensional
FNCs derived from waste plastics, detailing synthesis techniques such as
chemical vapor deposition, pyrolysis/catalytic pyrolysis, and
hydrothermal carbonization, along with the underlying mechanisms. Key
factors influencing the conversion process-including pressure,
temperature, and catalytic systems-are thoroughly examined. Discussions
on morphology and surface chemistry shed light on strategies to optimize
material properties for specific applications. Special attention is
given to the performance of FNCs in supercapacitors and batteries, using
benchmarks such as electrical conductivity, specific surface area, and
cycling stability to evaluate their suitability for energy storage.
Additionally, the review incorporates a circular economic perspective,
offering insights into how upcycling waste plastics into FNCs can
contribute to a more sustainable future. It identifies critical research
gaps, evaluates the environmental impacts of these processes, and
highlights promising opportunities for innovation. By fostering
interdisciplinary collaboration and bridging knowledge gaps, this review
aims to inspire advancements in both waste plastic upcycling and energy
technologies, ultimately contributing to sustainable solutions for
urgent environmental and energy challenges. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFChetna Tewari
Kundan Singh Rawat
Youngnam Kim
Tanuja Arya
Sunil Dhali
Sravendra Rana
Daria V Andreeva
Barbaros Ozyilmaz
Remi Mahfouz
Nada Qari
Yong Chae Jung
Nanda Gopal Sahoo
Kostya S Novoselov
- TIFunctional nanocarbons from waste plastics for energy storage
applications - SORENEWABLE & SUSTAINABLE ENERGY REVIEWS
- DTArticle
- ABThe mismanagement of waste plastic could lead to significant
environmental challenge, underscoring the urgent need for adopting
innovative strategies that will address its management and utilization.
At the same time, the growing demand for sustainable energy storage
materials necessitates the exploration of resourceful solutions
including advanced plastic-based materials. Addressing these dual
concerns, this review examines the transformation of waste plastics into
functional nanocarbons (FNCs) for energy-related applications. This
review provides a comprehensive analysis of zero-to-three-dimensional
FNCs derived from waste plastics, detailing synthesis techniques such as
chemical vapor deposition, pyrolysis/catalytic pyrolysis, and
hydrothermal carbonization, along with the underlying mechanisms. Key
factors influencing the conversion process-including pressure,
temperature, and catalytic systems-are thoroughly examined. Discussions
on morphology and surface chemistry shed light on strategies to optimize
material properties for specific applications. Special attention is
given to the performance of FNCs in supercapacitors and batteries, using
benchmarks such as electrical conductivity, specific surface area, and
cycling stability to evaluate their suitability for energy storage.
Additionally, the review incorporates a circular economic perspective,
offering insights into how upcycling waste plastics into FNCs can
contribute to a more sustainable future. It identifies critical research
gaps, evaluates the environmental impacts of these processes, and
highlights promising opportunities for innovation. By fostering
interdisciplinary collaboration and bridging knowledge gaps, this review
aims to inspire advancements in both waste plastic upcycling and energy
technologies, ultimately contributing to sustainable solutions for
urgent environmental and energy challenges. - Z94
- PUPERGAMON-ELSEVIER SCIENCE LTD
- PATHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
- SN1364-0321
- VL226
- DI10.1016/j.rser.2025.116443
- UTWOS:001614303300001
- ER
- EF
|
Shi, Lu; Zhang, Hanning; Grebenko, Artem K; Yamaletdinov, Ruslan; Rejaul, S K; Shivajirao, Ranjith; Tong, Zheng Jue; Luchkin, Sergey; Zhang, Hongji; Iakoubovskii, Konstantin V; Alekseeva, Alena A; Starkov, Andrei; Orofeo, Carlo M; Lin, Junhao; Suenaga, Kazutomo; Toh, Chee-Tat; Mahfouz, Remi; Tayeb, Talah M; Qari, Nada; Adams, Stefan; Weber, Bent; Yazyev, Oleg V; Ozyilmaz, Barbaros Monolayer Amorphous Carbon: Unlocking Disorder-Induced Lithiophilicity ADVANCED SCIENCE, 13 (3), 2026, DOI: 10.1002/advs.202516490. Abstract | BibTeX | Endnote @article{WOS:001622287600001,
title = {Monolayer Amorphous Carbon: Unlocking Disorder-Induced Lithiophilicity},
author = {Lu Shi and Hanning Zhang and Artem K Grebenko and Ruslan Yamaletdinov and S K Rejaul and Ranjith Shivajirao and Zheng Jue Tong and Sergey Luchkin and Hongji Zhang and Konstantin V Iakoubovskii and Alena A Alekseeva and Andrei Starkov and Carlo M Orofeo and Junhao Lin and Kazutomo Suenaga and Chee-Tat Toh and Remi Mahfouz and Talah M Tayeb and Nada Qari and Stefan Adams and Bent Weber and Oleg V Yazyev and Barbaros Ozyilmaz},
doi = {10.1002/advs.202516490},
times_cited = {2},
year = {2026},
date = {2026-01-01},
journal = {ADVANCED SCIENCE},
volume = {13},
number = {3},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {Dendritic lithium growth on the current collector remains a major
obstacle to developing anode-less batteries, arising from inhomogeneous
lithium nucleation and uneven surface lithiophilicity. Existing
approaches, such as metallic or carbonaceous interlayers, often fail to
stabilize lithium deposition due to mechanical degradation or spatial
variations in lithium affinity. Here, we demonstrate that a monolayer
amorphous carbon (MAC) film-a single-atom-thick disordered sp2 network
grown directly on copper-can fundamentally alter lithium nucleation
behavior. The topological disorder of MAC produces a dense distribution
of electron-rich sites that uniformly strengthen lithium binding. As a
result, the MAC surface exhibits a lithium contact angle of 31 +/- 5
degrees, four times lower than that of graphene and nearly three times
lower than that of bare copper, leading to homogeneous wetting and
deposition. Electrochemical tests reveal a reduced nucleation
overpotential of 28.9 mV at 0.5 mA cm-2. Density functional theory and
scanning tunneling microscopy confirm that disorder-induced localization
of states near the Fermi level enhances electronegativity and forms
continuous lithium-binding sites. These findings establish intrinsic
structural disorder, rather than chemical doping, as an effective route
to designing uniformly lithiophilic current collectors for
next-generation anode-less batteries.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Dendritic lithium growth on the current collector remains a major
obstacle to developing anode-less batteries, arising from inhomogeneous
lithium nucleation and uneven surface lithiophilicity. Existing
approaches, such as metallic or carbonaceous interlayers, often fail to
stabilize lithium deposition due to mechanical degradation or spatial
variations in lithium affinity. Here, we demonstrate that a monolayer
amorphous carbon (MAC) film-a single-atom-thick disordered sp2 network
grown directly on copper-can fundamentally alter lithium nucleation
behavior. The topological disorder of MAC produces a dense distribution
of electron-rich sites that uniformly strengthen lithium binding. As a
result, the MAC surface exhibits a lithium contact angle of 31 +/- 5
degrees, four times lower than that of graphene and nearly three times
lower than that of bare copper, leading to homogeneous wetting and
deposition. Electrochemical tests reveal a reduced nucleation
overpotential of 28.9 mV at 0.5 mA cm-2. Density functional theory and
scanning tunneling microscopy confirm that disorder-induced localization
of states near the Fermi level enhances electronegativity and forms
continuous lithium-binding sites. These findings establish intrinsic
structural disorder, rather than chemical doping, as an effective route
to designing uniformly lithiophilic current collectors for
next-generation anode-less batteries. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFLu Shi
Hanning Zhang
Artem K Grebenko
Ruslan Yamaletdinov
S K Rejaul
Ranjith Shivajirao
Zheng Jue Tong
Sergey Luchkin
Hongji Zhang
Konstantin V Iakoubovskii
Alena A Alekseeva
Andrei Starkov
Carlo M Orofeo
Junhao Lin
Kazutomo Suenaga
Chee-Tat Toh
Remi Mahfouz
Talah M Tayeb
Nada Qari
Stefan Adams
Bent Weber
Oleg V Yazyev
Barbaros Ozyilmaz
- TIMonolayer Amorphous Carbon: Unlocking Disorder-Induced Lithiophilicity
- SOADVANCED SCIENCE
- DTArticle
- ABDendritic lithium growth on the current collector remains a major
obstacle to developing anode-less batteries, arising from inhomogeneous
lithium nucleation and uneven surface lithiophilicity. Existing
approaches, such as metallic or carbonaceous interlayers, often fail to
stabilize lithium deposition due to mechanical degradation or spatial
variations in lithium affinity. Here, we demonstrate that a monolayer
amorphous carbon (MAC) film-a single-atom-thick disordered sp2 network
grown directly on copper-can fundamentally alter lithium nucleation
behavior. The topological disorder of MAC produces a dense distribution
of electron-rich sites that uniformly strengthen lithium binding. As a
result, the MAC surface exhibits a lithium contact angle of 31 +/- 5
degrees, four times lower than that of graphene and nearly three times
lower than that of bare copper, leading to homogeneous wetting and
deposition. Electrochemical tests reveal a reduced nucleation
overpotential of 28.9 mV at 0.5 mA cm-2. Density functional theory and
scanning tunneling microscopy confirm that disorder-induced localization
of states near the Fermi level enhances electronegativity and forms
continuous lithium-binding sites. These findings establish intrinsic
structural disorder, rather than chemical doping, as an effective route
to designing uniformly lithiophilic current collectors for
next-generation anode-less batteries. - Z92
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- VL13
- DI10.1002/advs.202516490
- UTWOS:001622287600001
- ER
- EF
|
2025
|
Zhang, Deqiang; Yeo, Jing Ying; Zhang, Hanning; Yamaletdinov, Ruslan; Yang, Qian; Zhan, Yufeng; Martin-Fernandez, Inigo; Yazyev, Oleg V; Toh, Chee-Tat; Ozyilmaz, Barbaros Dry Transfer of CVD Graphene Film Using Adhesion Switchable
Ferroelectric Polymers ADVANCED MATERIALS, 37 (50, SI), 2025, DOI: 10.1002/adma.202510545. Abstract | BibTeX | Endnote @article{WOS:001618079400001,
title = {Dry Transfer of CVD Graphene Film Using Adhesion Switchable
Ferroelectric Polymers},
author = {Deqiang Zhang and Jing Ying Yeo and Hanning Zhang and Ruslan Yamaletdinov and Qian Yang and Yufeng Zhan and Inigo Martin-Fernandez and Oleg V Yazyev and Chee-Tat Toh and Barbaros Ozyilmaz},
doi = {10.1002/adma.202510545},
times_cited = {1},
issn = {0935-9648},
year = {2025},
date = {2025-12-01},
journal = {ADVANCED MATERIALS},
volume = {37},
number = {50, SI},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {Although chemical vapor deposition (CVD) produces meter-scale,
high-quality graphene (Gr) on copper (Cu) foils, its practical
integration is hampered by challenges in the transfer process.
Conventional wet transfers are slow, produce chemical waste, and lack
scalability, whereas existing dry transfer methods struggle with
mechanical damage and residues due to strong Gr-Cu adhesion and the
difficulty in precisely tuning interfacial forces. Here, a fully dry,
industrially compatible transfer platform utilizing a ferroelectric
poly(vinylidene-fluoride-trifluoroethylene) (P(VDF-TrFE)) film with
electrostatically switchable adhesion, serving as both a mechanical
support and a transfer layer, is demonstrated. Negative Corona poling of
P(VDF-TrFE) induces p-type doping in graphene. Density Functional Theory
calculations confirm that this simultaneously reduces Gr-Cu adhesion
while increasing P(VDF-TrFE)-Gr adhesion, enabling clean, large-scale
graphene delamination from Cu foils with >99% coverage. Subsequent
thermal annealing above P(VDF-TrFE)'s Curie temperature (approximate to
135 degrees C) depolarizes the film, neutralizing the interfacial charge
for a clean release. The versatility of this method is shown for other
two-dimensional (2D) materials, including molybdenum disulfide and
hexagonal boron nitride. Crucially, the process has been validated on
cm-scale samples using a fully automated system with a transfer time of
<5 min, highlighting a viable path toward industrial-scale production of
high-quality 2D material films.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Although chemical vapor deposition (CVD) produces meter-scale,
high-quality graphene (Gr) on copper (Cu) foils, its practical
integration is hampered by challenges in the transfer process.
Conventional wet transfers are slow, produce chemical waste, and lack
scalability, whereas existing dry transfer methods struggle with
mechanical damage and residues due to strong Gr-Cu adhesion and the
difficulty in precisely tuning interfacial forces. Here, a fully dry,
industrially compatible transfer platform utilizing a ferroelectric
poly(vinylidene-fluoride-trifluoroethylene) (P(VDF-TrFE)) film with
electrostatically switchable adhesion, serving as both a mechanical
support and a transfer layer, is demonstrated. Negative Corona poling of
P(VDF-TrFE) induces p-type doping in graphene. Density Functional Theory
calculations confirm that this simultaneously reduces Gr-Cu adhesion
while increasing P(VDF-TrFE)-Gr adhesion, enabling clean, large-scale
graphene delamination from Cu foils with >99% coverage. Subsequent
thermal annealing above P(VDF-TrFE)'s Curie temperature (approximate to
135 degrees C) depolarizes the film, neutralizing the interfacial charge
for a clean release. The versatility of this method is shown for other
two-dimensional (2D) materials, including molybdenum disulfide and
hexagonal boron nitride. Crucially, the process has been validated on
cm-scale samples using a fully automated system with a transfer time of
<5 min, highlighting a viable path toward industrial-scale production of
high-quality 2D material films. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFDeqiang Zhang
Jing Ying Yeo
Hanning Zhang
Ruslan Yamaletdinov
Qian Yang
Yufeng Zhan
Inigo Martin-Fernandez
Oleg V Yazyev
Chee-Tat Toh
Barbaros Ozyilmaz
- TIDry Transfer of CVD Graphene Film Using Adhesion Switchable
Ferroelectric Polymers - SOADVANCED MATERIALS
- DTArticle
- ABAlthough chemical vapor deposition (CVD) produces meter-scale,
high-quality graphene (Gr) on copper (Cu) foils, its practical
integration is hampered by challenges in the transfer process.
Conventional wet transfers are slow, produce chemical waste, and lack
scalability, whereas existing dry transfer methods struggle with
mechanical damage and residues due to strong Gr-Cu adhesion and the
difficulty in precisely tuning interfacial forces. Here, a fully dry,
industrially compatible transfer platform utilizing a ferroelectric
poly(vinylidene-fluoride-trifluoroethylene) (P(VDF-TrFE)) film with
electrostatically switchable adhesion, serving as both a mechanical
support and a transfer layer, is demonstrated. Negative Corona poling of
P(VDF-TrFE) induces p-type doping in graphene. Density Functional Theory
calculations confirm that this simultaneously reduces Gr-Cu adhesion
while increasing P(VDF-TrFE)-Gr adhesion, enabling clean, large-scale
graphene delamination from Cu foils with >99% coverage. Subsequent
thermal annealing above P(VDF-TrFE)'s Curie temperature (approximate to
135 degrees C) depolarizes the film, neutralizing the interfacial charge
for a clean release. The versatility of this method is shown for other
two-dimensional (2D) materials, including molybdenum disulfide and
hexagonal boron nitride. Crucially, the process has been validated on
cm-scale samples using a fully automated system with a transfer time of
<5 min, highlighting a viable path toward industrial-scale production of
high-quality 2D material films. - Z91
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- SN0935-9648
- VL37
- DI10.1002/adma.202510545
- UTWOS:001618079400001
- ER
- EF
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