Bong, Jia Hui; Grebenchuk, Sergey; Nikolaev, Konstantin G; Chee, Celestine P T; Yang, Kou; Chen, Siyu; Baranov, Denis; Woods, Colin R; Andreeva, Daria V; Novoselov, Kostya S Graphene oxide-DNA/graphene oxide-PDDA sandwiched membranes with neuromorphic function NANOSCALE HORIZONS, 9 (5), pp. 863-872, 2024, DOI: 10.1039/d3nh00570d. Abstract | BibTeX | Endnote @article{ISI:001191219100001,
title = {Graphene oxide-DNA/graphene oxide-PDDA sandwiched membranes with neuromorphic function},
author = {Jia Hui Bong and Sergey Grebenchuk and Konstantin G Nikolaev and Celestine P T Chee and Kou Yang and Siyu Chen and Denis Baranov and Colin R Woods and Daria V Andreeva and Kostya S Novoselov},
doi = {10.1039/d3nh00570d},
times_cited = {1},
issn = {2055-6756},
year = {2024},
date = {2024-03-27},
journal = {NANOSCALE HORIZONS},
volume = {9},
number = {5},
pages = {863-872},
publisher = {ROYAL SOC CHEMISTRY},
address = {THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND},
abstract = {The behavior of polyelectrolytes in confined spaces has direct relevance to the protein mediated ion transport in living organisms. In this paper, we govern lithium chloride transport by the interface provided by polyelectrolytes, polycation, poly(diallyldimethylammonium chloride) (PDDA) and, polyanion, double stranded deoxyribonucleic acid (dsDNA), in confined graphene oxide (GO) membranes. Polyelectrolyte-GO interfaces demonstrate neuromorphic functions that were successfully applied with nanochannel ion interactions contributed, resulting in ion memory effects. Excitatory and inhibitory post-synaptic currents were tuned continuously as the number of pulses applied increased accordingly, increasing decay times. Furthermore, we demonstrated the short-term memory of a trained vs untrained device in computation. On account of its simple and safe production along with its robustness and stability, we anticipate our device to be a low dimensional building block for arrays to embed artificial neural networks in hardware for neuromorphic computing. Additionally, incorporating such devices with sensing and actuating parts for a complete feedback loop produces robotics with its own ability to learn by modifying actuation based on sensing data.},
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The behavior of polyelectrolytes in confined spaces has direct relevance to the protein mediated ion transport in living organisms. In this paper, we govern lithium chloride transport by the interface provided by polyelectrolytes, polycation, poly(diallyldimethylammonium chloride) (PDDA) and, polyanion, double stranded deoxyribonucleic acid (dsDNA), in confined graphene oxide (GO) membranes. Polyelectrolyte-GO interfaces demonstrate neuromorphic functions that were successfully applied with nanochannel ion interactions contributed, resulting in ion memory effects. Excitatory and inhibitory post-synaptic currents were tuned continuously as the number of pulses applied increased accordingly, increasing decay times. Furthermore, we demonstrated the short-term memory of a trained vs untrained device in computation. On account of its simple and safe production along with its robustness and stability, we anticipate our device to be a low dimensional building block for arrays to embed artificial neural networks in hardware for neuromorphic computing. Additionally, incorporating such devices with sensing and actuating parts for a complete feedback loop produces robotics with its own ability to learn by modifying actuation based on sensing data. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AUBong, JH
Grebenchuk, S
Nikolaev, KG
Chee, CPT
Yang, K
Chen, SY
Baranov, D
Woods, CR
Andreeva, DV
Novoselov, KS
- AFJia Hui Bong
Sergey Grebenchuk
Konstantin G Nikolaev
Celestine P T Chee
Kou Yang
Siyu Chen
Denis Baranov
Colin R Woods
Daria V Andreeva
Kostya S Novoselov
- TIGraphene oxide-DNA/graphene oxide-PDDA sandwiched membranes with neuromorphic function
- SONANOSCALE HORIZONS
- LAEnglish
- DTArticle
- IDLOW-VOLTAGE; SYNAPSES; NETWORK; NEURONS; DNA; PH
- ABThe behavior of polyelectrolytes in confined spaces has direct relevance to the protein mediated ion transport in living organisms. In this paper, we govern lithium chloride transport by the interface provided by polyelectrolytes, polycation, poly(diallyldimethylammonium chloride) (PDDA) and, polyanion, double stranded deoxyribonucleic acid (dsDNA), in confined graphene oxide (GO) membranes. Polyelectrolyte-GO interfaces demonstrate neuromorphic functions that were successfully applied with nanochannel ion interactions contributed, resulting in ion memory effects. Excitatory and inhibitory post-synaptic currents were tuned continuously as the number of pulses applied increased accordingly, increasing decay times. Furthermore, we demonstrated the short-term memory of a trained vs untrained device in computation. On account of its simple and safe production along with its robustness and stability, we anticipate our device to be a low dimensional building block for arrays to embed artificial neural networks in hardware for neuromorphic computing. Additionally, incorporating such devices with sensing and actuating parts for a complete feedback loop produces robotics with its own ability to learn by modifying actuation based on sensing data.
- C3National University of Singapore; Institute for Functional Intelligent Materials (I-FIM); National University of Singapore
- RPAndreeva, DV (corresponding author), Natl Univ Singapore, Inst Funct Intelligent Mat, Singapore 117544, Singapore; Andreeva, DV (corresponding author), Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117575, Singapore
- FXThis research is supported by the Ministry of Education, Singapore, under its Research Centre of Excellence award to the Institute for Functional Intelligent Materials (I-FIM, project no. EDUNC-33-18-279-V12).
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Costa, Mariana C F; Ng, Pei Rou; Grebenchuck, Sergey; Tan, Jun You; Koon, Gavin K W; Tan, Hui Li; Woods, Colin R; Donato, Ricardo K; Novoselov, Kostya S; Neto, Antonio Castro H Colossal enhancement of electrical and mechanical properties of graphene nanoscrolls CARBON, 208 , pp. 140-147, 2023, DOI: 10.1016/j.carbon.2023.03.025. Abstract | BibTeX | Endnote @article{ISI:000973042300001,
title = {Colossal enhancement of electrical and mechanical properties of graphene nanoscrolls},
author = {Mariana C F Costa and Pei Rou Ng and Sergey Grebenchuck and Jun You Tan and Gavin K W Koon and Hui Li Tan and Colin R Woods and Ricardo K Donato and Kostya S Novoselov and Antonio Castro H Neto},
doi = {10.1016/j.carbon.2023.03.025},
times_cited = {4},
issn = {0008-6223},
year = {2023},
date = {2023-03-29},
journal = {CARBON},
volume = {208},
pages = {140-147},
publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
abstract = {One of the most important characteristics of two-dimensional (2D) electrolytes [1] is their ability to reversibly transform into one-dimensional (1D) structures, such as nanoscrolls. However, when formed, these 1D structures are soft and unstable (because of the weak internal chemical bonds) and poorly electrically conducting (since chemical functionalization introduces a large degree of disorder in the 2D material basal plane). Using Peak-ForceTM quantitative nano-mechanics (PF-QNMTM) mode in atomic force microscopy (AFM) and electrical transport measurements, we demonstrate that a one-step, catalyst-free, graphitization of 1D graphene nano-scrolls leads to an enhanced structural stability (an increase of 6 times in the Young's modulus) and a dramatic reduction of structural disorder (observed by a resulting 5 orders of magnitude reduction of the electrical resistance) These large changes in physical properties open up the doors for the use of 1D graphene nanoscrolls in the study of exotic materials in 1D as well as a plethora of possible industrial applications, such as hydrogen and energy storage, akin to carbon nanotubes but with a much bigger flexibility in terms of morphologies and functionalities.},
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One of the most important characteristics of two-dimensional (2D) electrolytes [1] is their ability to reversibly transform into one-dimensional (1D) structures, such as nanoscrolls. However, when formed, these 1D structures are soft and unstable (because of the weak internal chemical bonds) and poorly electrically conducting (since chemical functionalization introduces a large degree of disorder in the 2D material basal plane). Using Peak-ForceTM quantitative nano-mechanics (PF-QNMTM) mode in atomic force microscopy (AFM) and electrical transport measurements, we demonstrate that a one-step, catalyst-free, graphitization of 1D graphene nano-scrolls leads to an enhanced structural stability (an increase of 6 times in the Young's modulus) and a dramatic reduction of structural disorder (observed by a resulting 5 orders of magnitude reduction of the electrical resistance) These large changes in physical properties open up the doors for the use of 1D graphene nanoscrolls in the study of exotic materials in 1D as well as a plethora of possible industrial applications, such as hydrogen and energy storage, akin to carbon nanotubes but with a much bigger flexibility in terms of morphologies and functionalities. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AUCosta, MCF
Ng, PR
Grebenchuck, S
Tan, JY
Koon, GKW
Li Tan, H
Woods, CR
Donato, RK
Novoselov, KS
Neto, AHC
- AFMariana C F Costa
Pei Rou Ng
Sergey Grebenchuck
Jun You Tan
Gavin K W Koon
Hui Li Tan
Colin R Woods
Ricardo K Donato
Kostya S Novoselov
Antonio Castro H Neto
- TIColossal enhancement of electrical and mechanical properties of graphene nanoscrolls
- SOCARBON
- LAEnglish
- DTArticle
- DE2D Electrolytes; Graphene Nanoscrolls; Electrical Properties; Mechanical Properties; Graphitization
- IDCARBON NANOTUBES; FACILE PREPARATION; RESISTANCE; OXIDE; FABRICATION; FILMS
- ABOne of the most important characteristics of two-dimensional (2D) electrolytes [1] is their ability to reversibly transform into one-dimensional (1D) structures, such as nanoscrolls. However, when formed, these 1D structures are soft and unstable (because of the weak internal chemical bonds) and poorly electrically conducting (since chemical functionalization introduces a large degree of disorder in the 2D material basal plane). Using Peak-ForceTM quantitative nano-mechanics (PF-QNMTM) mode in atomic force microscopy (AFM) and electrical transport measurements, we demonstrate that a one-step, catalyst-free, graphitization of 1D graphene nano-scrolls leads to an enhanced structural stability (an increase of 6 times in the Young's modulus) and a dramatic reduction of structural disorder (observed by a resulting 5 orders of magnitude reduction of the electrical resistance) These large changes in physical properties open up the doors for the use of 1D graphene nanoscrolls in the study of exotic materials in 1D as well as a plethora of possible industrial applications, such as hydrogen and energy storage, akin to carbon nanotubes but with a much bigger flexibility in terms of morphologies and functionalities.
- C3National University of Singapore; National University of Singapore; National University of Singapore
- RPCosta, MCF (corresponding author), Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117575, Singapore; Costa, MCF (corresponding author), Natl Univ Singapore, Ctr Adv 2D Mat, Singapore 117546, Singapore
- FXThis work was supported under the Medium-Sized Centre (MSC) grant from the National Research Foundation (NRF) of Singapore, Prime Minister's Office. This research was also supported by the Ministry of Education, Singapore, under its Research Centre of Excellence award to the Institute for Functional Intelligent Materials (I-FIM, project No. EDUNC-33-18-279-V12) .
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Latychevskaia, Tatiana; Woods, Colin Robert; Wang, Yi Bo; Holwill, Matthew; Prestat, Eric; Mustafi, Sara; Haigh, Sarah J; Novoselov, Konstantin S Potentials of individual atoms by convergent beam electron diffraction CARBON, 201 , pp. 244-250, 2022, DOI: 10.1016/j.carbon.2022.09.003. Abstract | BibTeX | Endnote @article{ISI:000860497200006,
title = {Potentials of individual atoms by convergent beam electron diffraction},
author = {Tatiana Latychevskaia and Colin Robert Woods and Yi Bo Wang and Matthew Holwill and Eric Prestat and Sara Mustafi and Sarah J Haigh and Konstantin S Novoselov},
doi = {10.1016/j.carbon.2022.09.003},
times_cited = {1},
issn = {0008-6223},
year = {2022},
date = {2022-09-19},
journal = {CARBON},
volume = {201},
pages = {244-250},
publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
abstract = {In convergent beam electron diffraction (CBED) on two-dimensional (2D) materials, the intensity distributions within the individual CBED spots map the local atomic arrangements within the probed region. In this study we demonstrate that the average intensities within the CBED spots essentially depend on the scattering parameters by a single atom, thus, offering the possibility of the direct measurement of such parameters. Scattering potential of an individual atom can be approximated by the Gaussian function and its parameters, the standard deviation and the maximal phase shift, can be recovered from the ratio of the intensities in the zero-and higher orders spots in CBED pattern. In order to demonstrate this, we simulated CBED patterns and extracted the atomic scattering parameters from such patterns. In the simulated examples, no weak phase object approximation is applied and the proposed method provides accurate results even for materials with large phase shifts up to 1.5 rad, as for example tungsten. The scattering parameters recovered from the experimental CBED patterns of graphene and twisted graphene-hBN structure show good agreement with the theoretically obtained values.},
keywords = {},
pubstate = {published},
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In convergent beam electron diffraction (CBED) on two-dimensional (2D) materials, the intensity distributions within the individual CBED spots map the local atomic arrangements within the probed region. In this study we demonstrate that the average intensities within the CBED spots essentially depend on the scattering parameters by a single atom, thus, offering the possibility of the direct measurement of such parameters. Scattering potential of an individual atom can be approximated by the Gaussian function and its parameters, the standard deviation and the maximal phase shift, can be recovered from the ratio of the intensities in the zero-and higher orders spots in CBED pattern. In order to demonstrate this, we simulated CBED patterns and extracted the atomic scattering parameters from such patterns. In the simulated examples, no weak phase object approximation is applied and the proposed method provides accurate results even for materials with large phase shifts up to 1.5 rad, as for example tungsten. The scattering parameters recovered from the experimental CBED patterns of graphene and twisted graphene-hBN structure show good agreement with the theoretically obtained values. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AULatychevskaia, T
Woods, CR
Wang, YB
Holwill, M
Prestat, E
Mustafi, S
Haigh, SJ
Novoselov, KS
- AFTatiana Latychevskaia
Colin Robert Woods
Yi Bo Wang
Matthew Holwill
Eric Prestat
Sara Mustafi
Sarah J Haigh
Konstantin S Novoselov
- TIPotentials of individual atoms by convergent beam electron diffraction
- SOCARBON
- LAEnglish
- DTArticle
- DEGraphene; Carbon; Atomic Potentials; Electron Microscopy; Convergent Beam Electron Diffraction
- IDPTYCHOGRAPHY
- ABIn convergent beam electron diffraction (CBED) on two-dimensional (2D) materials, the intensity distributions within the individual CBED spots map the local atomic arrangements within the probed region. In this study we demonstrate that the average intensities within the CBED spots essentially depend on the scattering parameters by a single atom, thus, offering the possibility of the direct measurement of such parameters. Scattering potential of an individual atom can be approximated by the Gaussian function and its parameters, the standard deviation and the maximal phase shift, can be recovered from the ratio of the intensities in the zero-and higher orders spots in CBED pattern. In order to demonstrate this, we simulated CBED patterns and extracted the atomic scattering parameters from such patterns. In the simulated examples, no weak phase object approximation is applied and the proposed method provides accurate results even for materials with large phase shifts up to 1.5 rad, as for example tungsten. The scattering parameters recovered from the experimental CBED patterns of graphene and twisted graphene-hBN structure show good agreement with the theoretically obtained values.
- C1[Latychevskaia, Tatiana; Mustafi, Sara] Univ Zurich, Phys Dept, Zurich, Switzerland.
[Latychevskaia, Tatiana; Mustafi, Sara] Paul Scherrer Inst, Forschungsstr 111, CH-5232 Villigen, Switzerland. [Woods, Colin Robert; Wang, Yi Bo; Holwill, Matthew; Haigh, Sarah J.; Novoselov, Konstantin S.] Univ Manchester, Natl Graphene Inst, Oxford Rd, Manchester M13 9PL, England. [Woods, Colin Robert; Wang, Yi Bo; Holwill, Matthew; Prestat, Eric] Univ Manchester, Sch Phys & Astron, Oxford Rd, Manchester M13 9PL, England. [Haigh, Sarah J.] Univ Manchester, Dept Mat, Oxford Rd, Manchester M13 9PL, England. [Novoselov, Konstantin S.] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117575, Singapore. [Novoselov, Konstantin S.] Natl Univ Singapore, Inst Funct Intelligent Mat, Singapore 117544, Singapore. [Novoselov, Konstantin S.] Chongqing 2D Mat Inst, Chongqing 400714, Peoples R China - C3University of Zurich; Swiss Federal Institutes of Technology Domain; Paul Scherrer Institute; University of Manchester; University of Manchester; University of Manchester; National University of Singapore; Institute for Functional Intelligent Materials (I-FIM); National University of Singapore
- RPLatychevskaia, T (corresponding author), Univ Zurich, Phys Dept, Zurich, Switzerland
- FUMinistry of Education (Singapore) [EDUN C -33-18-279-V12]; EU Graphene Flagship Program [CNECTICT-604391]; European Research Council Synergy Grant Hetero2D [319277]; European Research Council Starting Grant EvoluTEM [715502]; Royal Society (UK) [RSRPR190000]; EPSRC [EP/S019367/1, EP/P026850/1, EP/N010345/1, EP/P009050/1, EP/S021531/1, TRANS2DTMD]; Swiss National Foundation Research Grant [200021_197107]; EPSRC [EP/S021531/1, EP/N010345/1, EP/P009050/1, EP/S019367/1]; Swiss National Science Foundation (SNF) [200021_197107]
- FXThe authors acknowledge support by the Ministry of Education (Singapore) through the Research Centre of Excellence program (Award EDUN C -33-18-279-V12, Institute for Functional Intelligent Materials) , EU Graphene Flagship Program (contract CNECTICT-604391) , European Research Council Synergy Grant Hetero2D (contract 319277) , European Research Council Starting Grant EvoluTEM (contract 715502) , the Royal Society (UK, grant number RSRPR190000) , EPSRC grants EP/S019367/1, EP/P026850/1 and EP/N010345/1, EP/P009050/1, EP/S021531/1, FLAG -ERA project TRANS2DTMD, Swiss National Foundation Research Grant 200021_197107.
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