2026
|
Ng, Pei Rou; Zhang, Yixin; Min, Tania Jim Jia; Liu, Xuan; Lin, Mo; Ivanov, Artemii S; Nikolaev, Konstantin G; Mahfouz, Remi; Tayeb, Talah M; Qari, Nada; Bazan, Guillermo C; Sorokin, Vitaly; Novoselov, Kostya S; Andreeva, Daria V Graphene and amorphous carbon coatings for nitinol cardiovascular stents
by direct chemical vapor deposition: A comparative insight MATERIALS & DESIGN, 265 , 2026, DOI: 10.1016/j.matdes.2026.115864. Abstract | BibTeX | Endnote @article{WOS:001728083400001,
title = {Graphene and amorphous carbon coatings for nitinol cardiovascular stents
by direct chemical vapor deposition: A comparative insight},
author = {Pei Rou Ng and Yixin Zhang and Tania Jim Jia Min and Xuan Liu and Mo Lin and Artemii S Ivanov and Konstantin G Nikolaev and Remi Mahfouz and Talah M Tayeb and Nada Qari and Guillermo C Bazan and Vitaly Sorokin and Kostya S Novoselov and Daria V. Andreeva},
doi = {10.1016/j.matdes.2026.115864},
times_cited = {0},
issn = {0264-1275},
year = {2026},
date = {2026-05-01},
journal = {MATERIALS & DESIGN},
volume = {265},
publisher = {ELSEVIER SCI LTD},
address = {125 London Wall, London, ENGLAND},
abstract = {Carbon-based coatings are promising for biomedical implants, including
vascular stents, but fabrication on metals often requires adhesion
interlayers or polymer-assisted transfer, increasing cost and
complexity. Here, we report a simple, ambient-pressure chemical vapor
deposition (CVD) process for the direct, interlayer-free growth of two
carbon coatings on nitinol (NiTi) stents: few-layer graphene (FLG/NiTi,
170 +/- 20 nm) and amorphous carbon (a-C/NiTi, 620 +/- 30 nm). Both
coatings significantly enhanced corrosion resistance, with protection
efficiencies of 83.78% for FLG/NiTi and 89.19% for a-C/NiTi. Vascular
cell assays revealed distinct and clinically relevant biological
responses. a-C/NiTi promoted vascular endothelial cell (VEC)
proliferation (+17.2% at 96 h relative to bare NiTi) while suppressing
vascular smooth muscle cell (VSMC) proliferation (-25%), a desirable
outcome as excessive VSMC growth drives in-stent restenosis, whereas
endothelialization supports vessel healing. In contrast, FLG/NiTi
inhibited proliferation of both cell types (>50% reduction for VECs).
All samples exhibited excellent hemocompatibility (hemolysis < 0.2%),
and a-C/NiTi reduced platelet surface coverage by 30% compared with
bare NiTi, beneficial for mitigating thrombosis. Inflammatory assessment
further showed a 73% reduction in TNF-alpha secretion on a-C/NiTi in
comparison to bare NiTi. Together, these results demonstrate an
interlayer/ polymer-free route to carbon-coated NiTi stents with tunable
biological performance.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Carbon-based coatings are promising for biomedical implants, including
vascular stents, but fabrication on metals often requires adhesion
interlayers or polymer-assisted transfer, increasing cost and
complexity. Here, we report a simple, ambient-pressure chemical vapor
deposition (CVD) process for the direct, interlayer-free growth of two
carbon coatings on nitinol (NiTi) stents: few-layer graphene (FLG/NiTi,
170 +/- 20 nm) and amorphous carbon (a-C/NiTi, 620 +/- 30 nm). Both
coatings significantly enhanced corrosion resistance, with protection
efficiencies of 83.78% for FLG/NiTi and 89.19% for a-C/NiTi. Vascular
cell assays revealed distinct and clinically relevant biological
responses. a-C/NiTi promoted vascular endothelial cell (VEC)
proliferation (+17.2% at 96 h relative to bare NiTi) while suppressing
vascular smooth muscle cell (VSMC) proliferation (-25%), a desirable
outcome as excessive VSMC growth drives in-stent restenosis, whereas
endothelialization supports vessel healing. In contrast, FLG/NiTi
inhibited proliferation of both cell types (>50% reduction for VECs).
All samples exhibited excellent hemocompatibility (hemolysis < 0.2%),
and a-C/NiTi reduced platelet surface coverage by 30% compared with
bare NiTi, beneficial for mitigating thrombosis. Inflammatory assessment
further showed a 73% reduction in TNF-alpha secretion on a-C/NiTi in
comparison to bare NiTi. Together, these results demonstrate an
interlayer/ polymer-free route to carbon-coated NiTi stents with tunable
biological performance. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFPei Rou Ng
Yixin Zhang
Tania Jim Jia Min
Xuan Liu
Mo Lin
Artemii S Ivanov
Konstantin G Nikolaev
Remi Mahfouz
Talah M Tayeb
Nada Qari
Guillermo C Bazan
Vitaly Sorokin
Kostya S Novoselov
Daria V. Andreeva
- TIGraphene and amorphous carbon coatings for nitinol cardiovascular stents
by direct chemical vapor deposition: A comparative insight - SOMATERIALS & DESIGN
- DTArticle
- ABCarbon-based coatings are promising for biomedical implants, including
vascular stents, but fabrication on metals often requires adhesion
interlayers or polymer-assisted transfer, increasing cost and
complexity. Here, we report a simple, ambient-pressure chemical vapor
deposition (CVD) process for the direct, interlayer-free growth of two
carbon coatings on nitinol (NiTi) stents: few-layer graphene (FLG/NiTi,
170 +/- 20 nm) and amorphous carbon (a-C/NiTi, 620 +/- 30 nm). Both
coatings significantly enhanced corrosion resistance, with protection
efficiencies of 83.78% for FLG/NiTi and 89.19% for a-C/NiTi. Vascular
cell assays revealed distinct and clinically relevant biological
responses. a-C/NiTi promoted vascular endothelial cell (VEC)
proliferation (+17.2% at 96 h relative to bare NiTi) while suppressing
vascular smooth muscle cell (VSMC) proliferation (-25%), a desirable
outcome as excessive VSMC growth drives in-stent restenosis, whereas
endothelialization supports vessel healing. In contrast, FLG/NiTi
inhibited proliferation of both cell types (>50% reduction for VECs).
All samples exhibited excellent hemocompatibility (hemolysis < 0.2%),
and a-C/NiTi reduced platelet surface coverage by 30% compared with
bare NiTi, beneficial for mitigating thrombosis. Inflammatory assessment
further showed a 73% reduction in TNF-alpha secretion on a-C/NiTi in
comparison to bare NiTi. Together, these results demonstrate an
interlayer/ polymer-free route to carbon-coated NiTi stents with tunable
biological performance. - Z90
- PUELSEVIER SCI LTD
- PA125 London Wall, London, ENGLAND
- SN0264-1275
- VL265
- DI10.1016/j.matdes.2026.115864
- UTWOS:001728083400001
- ER
- EF
|
Nikolaev, Konstantin G; Ivanov, Artemii; Wen, Han; Wang, Qian; Kravtsov, Mikhail; Bandurin, Denis A; Karim, Nazmul; Novoselov, Kostya S; Andreeva, Daria V One-Spot Synthesized Crystalline Graphene/PANI for Wearable Ionic
Transistor Textiles SMALL STRUCTURES, 7 (4), 2026, DOI: 10.1002/sstr.202500904. Abstract | BibTeX | Endnote @article{WOS:001751311800005,
title = {One-Spot Synthesized Crystalline Graphene/PANI for Wearable Ionic
Transistor Textiles},
author = {Konstantin G Nikolaev and Artemii Ivanov and Han Wen and Qian Wang and Mikhail Kravtsov and Denis A Bandurin and Nazmul Karim and Kostya S Novoselov and Daria V Andreeva},
doi = {10.1002/sstr.202500904},
times_cited = {0},
year = {2026},
date = {2026-04-01},
journal = {SMALL STRUCTURES},
volume = {7},
number = {4},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {Here, we report a one-spot, temperature-controlled AC
electropolymerization strategy for converting graphene oxide and aniline
into a crystalline, processable reduced graphene oxide (rGO)/polyaniline
(PANI) composite for wearable ionic transistor textiles. By tuning the
electropolymerization temperature from 4 degrees C to 55 degrees C under
a low-frequency triangular AC waveform, followed by mild postreduction,
conformal polycrystalline PANI nanodomains are grown directly on rGO
sheets. Low-temperature synthesis yields the highest structural ordering
and the lowest fraction of protonated imine species, directly linking
growth conditions to mixed ionic-electronic transport behavior. The
resulting rGO/PANI composite functions as an electrolyte-gated
transistor with stable operation and amplified gate response.
Furthermore, the composite can be stencil printed onto cotton textiles
to realize ratiometric Na+/K+ sensing at constant ionic strength,
highlighting its potential for scalable, wearable ion-sensing
architectures.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Here, we report a one-spot, temperature-controlled AC
electropolymerization strategy for converting graphene oxide and aniline
into a crystalline, processable reduced graphene oxide (rGO)/polyaniline
(PANI) composite for wearable ionic transistor textiles. By tuning the
electropolymerization temperature from 4 degrees C to 55 degrees C under
a low-frequency triangular AC waveform, followed by mild postreduction,
conformal polycrystalline PANI nanodomains are grown directly on rGO
sheets. Low-temperature synthesis yields the highest structural ordering
and the lowest fraction of protonated imine species, directly linking
growth conditions to mixed ionic-electronic transport behavior. The
resulting rGO/PANI composite functions as an electrolyte-gated
transistor with stable operation and amplified gate response.
Furthermore, the composite can be stencil printed onto cotton textiles
to realize ratiometric Na+/K+ sensing at constant ionic strength,
highlighting its potential for scalable, wearable ion-sensing
architectures. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFKonstantin G Nikolaev
Artemii Ivanov
Han Wen
Qian Wang
Mikhail Kravtsov
Denis A Bandurin
Nazmul Karim
Kostya S Novoselov
Daria V Andreeva
- TIOne-Spot Synthesized Crystalline Graphene/PANI for Wearable Ionic
Transistor Textiles - SOSMALL STRUCTURES
- DTArticle
- ABHere, we report a one-spot, temperature-controlled AC
electropolymerization strategy for converting graphene oxide and aniline
into a crystalline, processable reduced graphene oxide (rGO)/polyaniline
(PANI) composite for wearable ionic transistor textiles. By tuning the
electropolymerization temperature from 4 degrees C to 55 degrees C under
a low-frequency triangular AC waveform, followed by mild postreduction,
conformal polycrystalline PANI nanodomains are grown directly on rGO
sheets. Low-temperature synthesis yields the highest structural ordering
and the lowest fraction of protonated imine species, directly linking
growth conditions to mixed ionic-electronic transport behavior. The
resulting rGO/PANI composite functions as an electrolyte-gated
transistor with stable operation and amplified gate response.
Furthermore, the composite can be stencil printed onto cotton textiles
to realize ratiometric Na+/K+ sensing at constant ionic strength,
highlighting its potential for scalable, wearable ion-sensing
architectures. - Z90
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- VL7
- DI10.1002/sstr.202500904
- UTWOS:001751311800005
- ER
- EF
|
2025
|
Lee, Han Wei; Ivanov, Artemii; Grebenchuk, Sergey; Lin, Mo; Chen, Siyu; Wang, Qian; Yip, Benjamin Rui Peng; Bazan, Guillermo C; Trubyanov, Maxim; Novoselov, Kostya S; Andreeva, Daria V Additive Manufacturing of Energy Materials Using Self-Assembled Graphene
Oxide and Printable Resin SMALL, 21 (32), 2025, DOI: 10.1002/smll.202503438. Abstract | BibTeX | Endnote @article{WOS:001506802700001,
title = {Additive Manufacturing of Energy Materials Using Self-Assembled Graphene
Oxide and Printable Resin},
author = {Han Wei Lee and Artemii Ivanov and Sergey Grebenchuk and Mo Lin and Siyu Chen and Qian Wang and Benjamin Rui Peng Yip and Guillermo C Bazan and Maxim Trubyanov and Kostya S Novoselov and Daria V Andreeva},
doi = {10.1002/smll.202503438},
times_cited = {3},
issn = {1613-6810},
year = {2025},
date = {2025-08-01},
journal = {SMALL},
volume = {21},
number = {32},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {A strategy is reported for fabricating 3D-printed electrodes using
self-assembled graphene oxide (GO) core-shell microspheres as tunable
microreactors. This approach enables control over microsphere size and
shell thickness via pH adjustment and sonication parameters, yielding
either individual conductive particles or interconnected networks
suitable for Direct Ink Writing. Following pyrolysis, the resulting
hierarchically porous, rigid constructs exhibit surface area of 1000
m(2) g(-1) and compressive strengths up to 9.5 MPa - outperforming most
3D-printed carbon supercapacitor structures in mechanical robustness.
Electrochemically, the optimized architecture delivers 125 F g(-1), 1.4
F and 4.7 F cm(-3) in 1 m H2SO4, and maintains >95% of its capacity
after 30 000 cycles while preserving structural integrity. This method
combines bottom-up GO self-assembly with top-down additive manufacturing
to produce mechanically resilient, high-performance supercapacitor
electrodes - bridging nanoscale material design with macroscale energy
storage systems engineering.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
A strategy is reported for fabricating 3D-printed electrodes using
self-assembled graphene oxide (GO) core-shell microspheres as tunable
microreactors. This approach enables control over microsphere size and
shell thickness via pH adjustment and sonication parameters, yielding
either individual conductive particles or interconnected networks
suitable for Direct Ink Writing. Following pyrolysis, the resulting
hierarchically porous, rigid constructs exhibit surface area of 1000
m(2) g(-1) and compressive strengths up to 9.5 MPa - outperforming most
3D-printed carbon supercapacitor structures in mechanical robustness.
Electrochemically, the optimized architecture delivers 125 F g(-1), 1.4
F and 4.7 F cm(-3) in 1 m H2SO4, and maintains >95% of its capacity
after 30 000 cycles while preserving structural integrity. This method
combines bottom-up GO self-assembly with top-down additive manufacturing
to produce mechanically resilient, high-performance supercapacitor
electrodes - bridging nanoscale material design with macroscale energy
storage systems engineering. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFHan Wei Lee
Artemii Ivanov
Sergey Grebenchuk
Mo Lin
Siyu Chen
Qian Wang
Benjamin Rui Peng Yip
Guillermo C Bazan
Maxim Trubyanov
Kostya S Novoselov
Daria V Andreeva
- TIAdditive Manufacturing of Energy Materials Using Self-Assembled Graphene
Oxide and Printable Resin - SOSMALL
- DTArticle
- ABA strategy is reported for fabricating 3D-printed electrodes using
self-assembled graphene oxide (GO) core-shell microspheres as tunable
microreactors. This approach enables control over microsphere size and
shell thickness via pH adjustment and sonication parameters, yielding
either individual conductive particles or interconnected networks
suitable for Direct Ink Writing. Following pyrolysis, the resulting
hierarchically porous, rigid constructs exhibit surface area of 1000
m(2) g(-1) and compressive strengths up to 9.5 MPa - outperforming most
3D-printed carbon supercapacitor structures in mechanical robustness.
Electrochemically, the optimized architecture delivers 125 F g(-1), 1.4
F and 4.7 F cm(-3) in 1 m H2SO4, and maintains >95% of its capacity
after 30 000 cycles while preserving structural integrity. This method
combines bottom-up GO self-assembly with top-down additive manufacturing
to produce mechanically resilient, high-performance supercapacitor
electrodes - bridging nanoscale material design with macroscale energy
storage systems engineering. - Z93
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- SN1613-6810
- VL21
- DI10.1002/smll.202503438
- UTWOS:001506802700001
- ER
- EF
|
Chen, Siyu; Tan, Gladys Shi Xuan; Ivanov, Artemii; Savilov, Timofey M; Yang, Kou; Leng, Xuanye; Chen, Musen; Novoselov, Kostya S; Andreeva, Daria V Tunable anion transport and the chemical transistor effect in
functionalized graphene oxide membranes NPJ 2D MATERIALS AND APPLICATIONS, 9 (1), 2025, DOI: 10.1038/s41699-025-00585-x. Abstract | BibTeX | Endnote @article{WOS:001531987900002,
title = {Tunable anion transport and the chemical transistor effect in
functionalized graphene oxide membranes},
author = {Siyu Chen and Gladys Shi Xuan Tan and Artemii Ivanov and Timofey M Savilov and Kou Yang and Xuanye Leng and Musen Chen and Kostya S Novoselov and Daria V Andreeva},
doi = {10.1038/s41699-025-00585-x},
times_cited = {4},
year = {2025},
date = {2025-07-01},
journal = {NPJ 2D MATERIALS AND APPLICATIONS},
volume = {9},
number = {1},
publisher = {NATURE PORTFOLIO},
address = {HEIDELBERGER PLATZ 3, BERLIN, 14197, GERMANY},
abstract = {Selective anion transport is essential for energy conversion, water
purification, and electrochemical systems, yet achieving precise ion
selectivity in membranes remains a challenge. Here, we present an
amino-functionalized graphene oxide (am-GO) membrane that enables
tunable anion transport through nanochannels. Using a combined
experimental and computational approach, we consider the three stages of
ionic transport-absorption, diffusion, and desorption-to reveal that Cl-
selectively diffuses through nanochannels, while NO3-, SO42-, and PO43-
are excluded. In ionic mixtures, the chemical transistor effect emerges,
where Cl- pulls water from NO3- hydration shell, enhancing its mobility,
while SO42- and PO43- remain excluded due to size constraints. This
mechanism enables precisely regulated Cl- and NO3- transport, with
ultrahigh rejection rates of 99.99% for SO42- and PO43-, even in
complex ionic environments. The am-GO exhibits stability and
anion-hopping mechanisms, making it a versatile platform for anion
exchange membranes in electrolysis, energy storage, and environmental
applications.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Selective anion transport is essential for energy conversion, water
purification, and electrochemical systems, yet achieving precise ion
selectivity in membranes remains a challenge. Here, we present an
amino-functionalized graphene oxide (am-GO) membrane that enables
tunable anion transport through nanochannels. Using a combined
experimental and computational approach, we consider the three stages of
ionic transport-absorption, diffusion, and desorption-to reveal that Cl-
selectively diffuses through nanochannels, while NO3-, SO42-, and PO43-
are excluded. In ionic mixtures, the chemical transistor effect emerges,
where Cl- pulls water from NO3- hydration shell, enhancing its mobility,
while SO42- and PO43- remain excluded due to size constraints. This
mechanism enables precisely regulated Cl- and NO3- transport, with
ultrahigh rejection rates of 99.99% for SO42- and PO43-, even in
complex ionic environments. The am-GO exhibits stability and
anion-hopping mechanisms, making it a versatile platform for anion
exchange membranes in electrolysis, energy storage, and environmental
applications. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFSiyu Chen
Gladys Shi Xuan Tan
Artemii Ivanov
Timofey M Savilov
Kou Yang
Xuanye Leng
Musen Chen
Kostya S Novoselov
Daria V Andreeva
- TITunable anion transport and the chemical transistor effect in
functionalized graphene oxide membranes - SONPJ 2D MATERIALS AND APPLICATIONS
- DTArticle
- ABSelective anion transport is essential for energy conversion, water
purification, and electrochemical systems, yet achieving precise ion
selectivity in membranes remains a challenge. Here, we present an
amino-functionalized graphene oxide (am-GO) membrane that enables
tunable anion transport through nanochannels. Using a combined
experimental and computational approach, we consider the three stages of
ionic transport-absorption, diffusion, and desorption-to reveal that Cl-
selectively diffuses through nanochannels, while NO3-, SO42-, and PO43-
are excluded. In ionic mixtures, the chemical transistor effect emerges,
where Cl- pulls water from NO3- hydration shell, enhancing its mobility,
while SO42- and PO43- remain excluded due to size constraints. This
mechanism enables precisely regulated Cl- and NO3- transport, with
ultrahigh rejection rates of 99.99% for SO42- and PO43-, even in
complex ionic environments. The am-GO exhibits stability and
anion-hopping mechanisms, making it a versatile platform for anion
exchange membranes in electrolysis, energy storage, and environmental
applications. - Z94
- PUNATURE PORTFOLIO
- PAHEIDELBERGER PLATZ 3, BERLIN, 14197, GERMANY
- VL9
- DI10.1038/s41699-025-00585-x
- UTWOS:001531987900002
- ER
- EF
|
Lin, Mo; Trubyanov, Maxim; Lee, Han Wei; Ivanov, Artemii S; Zhou, Xin; Zhang, Pengxiang; Zhang, Yixin; Wang, Qian; Tan, Gladys Shi Xuan; Novoselov, Kostya S; Andreeva, Daria V Enhanced CO2 Hydrogenation to Methanol Using out-of-Plane
Grown MoS2 Flakes on Amorphous Carbon Scaffold 13 SMALL, 21 (11), 2025, DOI: 10.1002/smll.202408592. Abstract | BibTeX | Endnote @article{WOS:001420874000001,
title = {Enhanced CO2 Hydrogenation to Methanol Using out-of-Plane
Grown MoS2 Flakes on Amorphous Carbon Scaffold},
author = {Mo Lin and Maxim Trubyanov and Han Wei Lee and Artemii S Ivanov and Xin Zhou and Pengxiang Zhang and Yixin Zhang and Qian Wang and Gladys Shi Xuan Tan and Kostya S Novoselov and Daria V Andreeva},
doi = {10.1002/smll.202408592},
times_cited = {13},
issn = {1613-6810},
year = {2025},
date = {2025-03-01},
journal = {SMALL},
volume = {21},
number = {11},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {The conversion of excess carbon dioxide (CO2) into valuable chemicals is
critical for achieving a sustainable society. Among various catalysts,
molybdenum disulfide (MoS2) has demonstrated potential for CO2
hydrogenation to methanol. However, its catalytic activity has yet to be
fully optimized, and scalable, industrially viable production methods
remain underdeveloped. In this work, a chemical vapor deposition (CVD)
approach is introduced to grow vertically oriented MoS2 crystals on an
amorphous carbon template. This method enhances the exposure of
vacancy-rich basal planes, which are crucial for stable catalytic
performance. The 2H-MoS2 flakes, supported on a conductive carbon
scaffold, exhibit catalytic activity, achieving a net space-time yield
of 2.68 g(MeOH) gcat(-)(1) h(-)(1) with a selectivity of 82.5% under
mild conditions (264 degrees C, 10 bar). This work highlights a
significant step toward the industrial application of MoS2-based
catalysts for CO2 conversion, bridging the gap between fundamental
research and scalable implementation.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The conversion of excess carbon dioxide (CO2) into valuable chemicals is
critical for achieving a sustainable society. Among various catalysts,
molybdenum disulfide (MoS2) has demonstrated potential for CO2
hydrogenation to methanol. However, its catalytic activity has yet to be
fully optimized, and scalable, industrially viable production methods
remain underdeveloped. In this work, a chemical vapor deposition (CVD)
approach is introduced to grow vertically oriented MoS2 crystals on an
amorphous carbon template. This method enhances the exposure of
vacancy-rich basal planes, which are crucial for stable catalytic
performance. The 2H-MoS2 flakes, supported on a conductive carbon
scaffold, exhibit catalytic activity, achieving a net space-time yield
of 2.68 g(MeOH) gcat(-)(1) h(-)(1) with a selectivity of 82.5% under
mild conditions (264 degrees C, 10 bar). This work highlights a
significant step toward the industrial application of MoS2-based
catalysts for CO2 conversion, bridging the gap between fundamental
research and scalable implementation. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFMo Lin
Maxim Trubyanov
Han Wei Lee
Artemii S Ivanov
Xin Zhou
Pengxiang Zhang
Yixin Zhang
Qian Wang
Gladys Shi Xuan Tan
Kostya S Novoselov
Daria V Andreeva
- TIEnhanced CO2 Hydrogenation to Methanol Using out-of-Plane
Grown MoS2 Flakes on Amorphous Carbon Scaffold - SOSMALL
- DTArticle
- ABThe conversion of excess carbon dioxide (CO2) into valuable chemicals is
critical for achieving a sustainable society. Among various catalysts,
molybdenum disulfide (MoS2) has demonstrated potential for CO2
hydrogenation to methanol. However, its catalytic activity has yet to be
fully optimized, and scalable, industrially viable production methods
remain underdeveloped. In this work, a chemical vapor deposition (CVD)
approach is introduced to grow vertically oriented MoS2 crystals on an
amorphous carbon template. This method enhances the exposure of
vacancy-rich basal planes, which are crucial for stable catalytic
performance. The 2H-MoS2 flakes, supported on a conductive carbon
scaffold, exhibit catalytic activity, achieving a net space-time yield
of 2.68 g(MeOH) gcat(-)(1) h(-)(1) with a selectivity of 82.5% under
mild conditions (264 degrees C, 10 bar). This work highlights a
significant step toward the industrial application of MoS2-based
catalysts for CO2 conversion, bridging the gap between fundamental
research and scalable implementation. - Z913
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- SN1613-6810
- VL21
- DI10.1002/smll.202408592
- UTWOS:001420874000001
- ER
- EF
|