2026
|
Limpo, Carlos Maria Alava; Lee, Jong Hak; Ong, Yong Kang; Sassi, Lucas M; Rao, Yifan; Shi, Lu; Poh, Eng Tuan; Tsuchiya, Keiji; Takahashi, Daichi; Ozyilmaz, Barbaros Pore interconnectivity as a design principle for durable high-voltage
carbon-based supercapacitors MICROSTRUCTURES, 6 (5), 2026, DOI: 10.20517/microstructures.2026.86. Abstract | BibTeX | Endnote @article{WOS:001882753900001,
title = {Pore interconnectivity as a design principle for durable high-voltage
carbon-based supercapacitors},
author = {Carlos Maria Alava Limpo and Jong Hak Lee and Yong Kang Ong and Lucas M Sassi and Yifan Rao and Lu Shi and Eng Tuan Poh and Keiji Tsuchiya and Daichi Takahashi and Barbaros Ozyilmaz},
doi = {10.20517/microstructures.2026.86},
times_cited = {0},
year = {2026},
date = {2026-10-01},
journal = {MICROSTRUCTURES},
volume = {6},
number = {5},
publisher = {OAE PUBLISHING INC},
address = {245 E MAIN ST, ST122, ALHAMBRA, CA 91801 USA},
abstract = {The occlusion of sorption sites during gradual electrochemical
degradation is widely implicated in the capacitance fade of carbon-based
supercapacitors, yet how pore architecture influences the tolerance of
electrodes to pore blocking remains insufficiently studied. This work
demonstrates that pore interconnectivity plays a key role in determining
the tolerance of carbon electrodes to site occlusion. Alongside
electrochemical tests, structural characterization of conventional
activated carbons revealed how their narrow micropores are susceptible
to accessibility loss while under potentiostatic operation, thus
suffering rapid capacitance losses and equivalent series resistance
(ESR) increments. In contrast, a carbon developed with a
well-interconnected micro-mesoporous network demonstrated up to 14-fold
longer lifetime under identical conditions. Critically, this improved
durability translated to an 11-fold increase in cumulative energy
delivered prior to End-of-Life of the device, as compared to carbons
whose structures are initially optimized for maximizing capacitance.
Further post-mortem analyses indicated that carbons with improved pore
interconnectivity can tolerate a greater buildup of pore-blocking
by-products before reaching capacitive failure, thus showing how pore
network architecture mitigates or exacerbates the progressive occlusion
of ion-accessible regions. We propose that highly interconnected pore
structures feature alternative pathways that maintain the accessibility
of sorption sites under constant operation. These findings establish
pore interconnectivity as a key principle for extending the durability
of supercapacitors under demanding voltage and temperature conditions.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The occlusion of sorption sites during gradual electrochemical
degradation is widely implicated in the capacitance fade of carbon-based
supercapacitors, yet how pore architecture influences the tolerance of
electrodes to pore blocking remains insufficiently studied. This work
demonstrates that pore interconnectivity plays a key role in determining
the tolerance of carbon electrodes to site occlusion. Alongside
electrochemical tests, structural characterization of conventional
activated carbons revealed how their narrow micropores are susceptible
to accessibility loss while under potentiostatic operation, thus
suffering rapid capacitance losses and equivalent series resistance
(ESR) increments. In contrast, a carbon developed with a
well-interconnected micro-mesoporous network demonstrated up to 14-fold
longer lifetime under identical conditions. Critically, this improved
durability translated to an 11-fold increase in cumulative energy
delivered prior to End-of-Life of the device, as compared to carbons
whose structures are initially optimized for maximizing capacitance.
Further post-mortem analyses indicated that carbons with improved pore
interconnectivity can tolerate a greater buildup of pore-blocking
by-products before reaching capacitive failure, thus showing how pore
network architecture mitigates or exacerbates the progressive occlusion
of ion-accessible regions. We propose that highly interconnected pore
structures feature alternative pathways that maintain the accessibility
of sorption sites under constant operation. These findings establish
pore interconnectivity as a key principle for extending the durability
of supercapacitors under demanding voltage and temperature conditions. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFCarlos Maria Alava Limpo
Jong Hak Lee
Yong Kang Ong
Lucas M Sassi
Yifan Rao
Lu Shi
Eng Tuan Poh
Keiji Tsuchiya
Daichi Takahashi
Barbaros Ozyilmaz
- TIPore interconnectivity as a design principle for durable high-voltage
carbon-based supercapacitors - SOMICROSTRUCTURES
- DTArticle
- ABThe occlusion of sorption sites during gradual electrochemical
degradation is widely implicated in the capacitance fade of carbon-based
supercapacitors, yet how pore architecture influences the tolerance of
electrodes to pore blocking remains insufficiently studied. This work
demonstrates that pore interconnectivity plays a key role in determining
the tolerance of carbon electrodes to site occlusion. Alongside
electrochemical tests, structural characterization of conventional
activated carbons revealed how their narrow micropores are susceptible
to accessibility loss while under potentiostatic operation, thus
suffering rapid capacitance losses and equivalent series resistance
(ESR) increments. In contrast, a carbon developed with a
well-interconnected micro-mesoporous network demonstrated up to 14-fold
longer lifetime under identical conditions. Critically, this improved
durability translated to an 11-fold increase in cumulative energy
delivered prior to End-of-Life of the device, as compared to carbons
whose structures are initially optimized for maximizing capacitance.
Further post-mortem analyses indicated that carbons with improved pore
interconnectivity can tolerate a greater buildup of pore-blocking
by-products before reaching capacitive failure, thus showing how pore
network architecture mitigates or exacerbates the progressive occlusion
of ion-accessible regions. We propose that highly interconnected pore
structures feature alternative pathways that maintain the accessibility
of sorption sites under constant operation. These findings establish
pore interconnectivity as a key principle for extending the durability
of supercapacitors under demanding voltage and temperature conditions. - Z90
- PUOAE PUBLISHING INC
- PA245 E MAIN ST, ST122, ALHAMBRA, CA 91801 USA
- VL6
- DI10.20517/microstructures.2026.86
- UTWOS:001882753900001
- ER
- EF
|
Toh, Chee-Tat; Grebenko, Artem K; Karadeniz, Ugur; Bhat, Usha; He, Ya; Zhang, Hongji; Shi, Lu; Rogov, Iurii; Noskova, Daria; Starkov, Andrei; Alekseeva, Alena A; Iakoubovskii, Konstantin V; Tee, Chuan Chu; Vyalikh, Denis V; Makarova, Anna; Fedorov, Alexander; Sassi, Lucas M; Bosman, Michel; Kamiuchi, Naoto; Sato, Yuta; Suenaga, Kazutomo; Ozyilmaz, Barbaros Atomically thin amorphous carbon with an ultralow dielectric constant NATURE ELECTRONICS, 9 (9), 2026, DOI: 10.1038/s41928-026-01685-2. Abstract | BibTeX | Endnote @article{WOS:001851851300001,
title = {Atomically thin amorphous carbon with an ultralow dielectric constant},
author = {Chee-Tat Toh and Artem K Grebenko and Ugur Karadeniz and Usha Bhat and Ya He and Hongji Zhang and Lu Shi and Iurii Rogov and Daria Noskova and Andrei Starkov and Alena A Alekseeva and Konstantin V Iakoubovskii and Chuan Chu Tee and Denis V Vyalikh and Anna Makarova and Alexander Fedorov and Lucas M Sassi and Michel Bosman and Naoto Kamiuchi and Yuta Sato and Kazutomo Suenaga and Barbaros Ozyilmaz},
doi = {10.1038/s41928-026-01685-2},
times_cited = {0},
issn = {2520-1131},
year = {2026},
date = {2026-09-01},
journal = {NATURE ELECTRONICS},
volume = {9},
number = {9},
publisher = {NATURE PORTFOLIO},
address = {HEIDELBERGER PLATZ 3, BERLIN, 14197, GERMANY},
abstract = {Two-dimensional (2D) materials could replace conventional electronic
components. Key advances have already been made in applying 2D materials
to integrated circuits, but a robust, atomically thin ultralow-k
dielectric remains crucial for further circuit scaling. Minimizing
parasitic capacitances, in particular, will be needed as conductor
spacing shrinks below 10 nm. However, conventional amorphous or porous
low-k dielectrics become unstable at nanometre thicknesses. Here we show
that atomically thin amorphous carbon films can function as mechanically
robust ultralow-k dielectrics with a dielectric constant of 1.35 and a
dielectric strength of 28-31 MV cm-1. The films are also an effective
barrier to metal-ion diffusion, with a time to failure of 1010 s at
0.8-nm thickness. Our approach relies on a low-temperature, direct and
conformal growth process, which makes it promising for practical
implementation in complementary metal-oxide-semiconductor technology.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Two-dimensional (2D) materials could replace conventional electronic
components. Key advances have already been made in applying 2D materials
to integrated circuits, but a robust, atomically thin ultralow-k
dielectric remains crucial for further circuit scaling. Minimizing
parasitic capacitances, in particular, will be needed as conductor
spacing shrinks below 10 nm. However, conventional amorphous or porous
low-k dielectrics become unstable at nanometre thicknesses. Here we show
that atomically thin amorphous carbon films can function as mechanically
robust ultralow-k dielectrics with a dielectric constant of 1.35 and a
dielectric strength of 28-31 MV cm-1. The films are also an effective
barrier to metal-ion diffusion, with a time to failure of 1010 s at
0.8-nm thickness. Our approach relies on a low-temperature, direct and
conformal growth process, which makes it promising for practical
implementation in complementary metal-oxide-semiconductor technology. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFChee-Tat Toh
Artem K Grebenko
Ugur Karadeniz
Usha Bhat
Ya He
Hongji Zhang
Lu Shi
Iurii Rogov
Daria Noskova
Andrei Starkov
Alena A Alekseeva
Konstantin V Iakoubovskii
Chuan Chu Tee
Denis V Vyalikh
Anna Makarova
Alexander Fedorov
Lucas M Sassi
Michel Bosman
Naoto Kamiuchi
Yuta Sato
Kazutomo Suenaga
Barbaros Ozyilmaz
- TIAtomically thin amorphous carbon with an ultralow dielectric constant
- SONATURE ELECTRONICS
- DTArticle
- ABTwo-dimensional (2D) materials could replace conventional electronic
components. Key advances have already been made in applying 2D materials
to integrated circuits, but a robust, atomically thin ultralow-k
dielectric remains crucial for further circuit scaling. Minimizing
parasitic capacitances, in particular, will be needed as conductor
spacing shrinks below 10 nm. However, conventional amorphous or porous
low-k dielectrics become unstable at nanometre thicknesses. Here we show
that atomically thin amorphous carbon films can function as mechanically
robust ultralow-k dielectrics with a dielectric constant of 1.35 and a
dielectric strength of 28-31 MV cm-1. The films are also an effective
barrier to metal-ion diffusion, with a time to failure of 1010 s at
0.8-nm thickness. Our approach relies on a low-temperature, direct and
conformal growth process, which makes it promising for practical
implementation in complementary metal-oxide-semiconductor technology. - Z90
- PUNATURE PORTFOLIO
- PAHEIDELBERGER PLATZ 3, BERLIN, 14197, GERMANY
- SN2520-1131
- VL9
- DI10.1038/s41928-026-01685-2
- UTWOS:001851851300001
- ER
- EF
|
Ji, Zekai; Jayakumar, Sanjeevi; Limpo, Carlos Maria Alava; Madhav, Aravind; Trubyanov, Maxim; Zhang, Pengxiang; V, Daria Andreeva; Lee, Jong Hak; Ozyilmaz, Barbaros 3D interconnected pore networks enable superior volumetric CO2
uptake in amine-functionalized nanoporous carbon for direct air
capture CARBON CAPTURE SCIENCE & TECHNOLOGY, 19 , 2026, DOI: 10.1016/j.ccst.2026.100600. Abstract | BibTeX | Endnote @article{WOS:001724390300001,
title = {3D interconnected pore networks enable superior volumetric CO2
uptake in amine-functionalized nanoporous carbon for direct air
capture},
author = {Zekai Ji and Sanjeevi Jayakumar and Carlos Maria Alava Limpo and Aravind Madhav and Maxim Trubyanov and Pengxiang Zhang and Daria Andreeva V and Jong Hak Lee and Barbaros Ozyilmaz},
doi = {10.1016/j.ccst.2026.100600},
times_cited = {0},
issn = {2772-6568},
year = {2026},
date = {2026-06-01},
journal = {CARBON CAPTURE SCIENCE & TECHNOLOGY},
volume = {19},
publisher = {ELSEVIER},
address = {RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS},
abstract = {Direct Air Capture (DAC) is a critical technology for mitigating
atmospheric CO2 concentrations, but current systems require substantial
space and high energy input, largely due to the low volumetric CO2
capture capacity of existing sorbents. A major limitation arises from
the intrinsic trade-off in conventional mesoporous platforms, where
increasing amine loading often compromises CO2 diffusion efficiency,
resulting in poor volumetric performance. In this report, we introduce a
solid-state sorbent platform that overcomes this limitation by
leveraging a fully interconnected three-dimensional (3D) pore network.
The sorbent, composed of polyethyleneimine (PEI)-functionalized
nanoporous amorphous carbon (NAC) millimeter-sized monoliths, features a
hierarchically organized pore architecture with high volumetric pore
density, enabling deep and uniform amine infiltration while maintaining
unobstructed CO2 diffusion pathways. This synergistic pore design yields
a remarkable volumetric CO2 uptake of similar to 1.6 mmol/cm & sup3;
under pre-hydrated conditions-over threefold higher than that of the
best-performing shaped sorbents reported to date. The NAC-PEI monoliths
further exhibit cyclic stability, mechanical robustness, and negligible
pressure drop, supporting their integration into compact and
energy-efficient continuous DAC modules. These findings establish pore
interconnectivity as a key design principle for next-generation solid
sorbents, enabling space-efficient, high-performance carbon removal
systems suitable for urban and distributed deployment.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Direct Air Capture (DAC) is a critical technology for mitigating
atmospheric CO2 concentrations, but current systems require substantial
space and high energy input, largely due to the low volumetric CO2
capture capacity of existing sorbents. A major limitation arises from
the intrinsic trade-off in conventional mesoporous platforms, where
increasing amine loading often compromises CO2 diffusion efficiency,
resulting in poor volumetric performance. In this report, we introduce a
solid-state sorbent platform that overcomes this limitation by
leveraging a fully interconnected three-dimensional (3D) pore network.
The sorbent, composed of polyethyleneimine (PEI)-functionalized
nanoporous amorphous carbon (NAC) millimeter-sized monoliths, features a
hierarchically organized pore architecture with high volumetric pore
density, enabling deep and uniform amine infiltration while maintaining
unobstructed CO2 diffusion pathways. This synergistic pore design yields
a remarkable volumetric CO2 uptake of similar to 1.6 mmol/cm & sup3;
under pre-hydrated conditions-over threefold higher than that of the
best-performing shaped sorbents reported to date. The NAC-PEI monoliths
further exhibit cyclic stability, mechanical robustness, and negligible
pressure drop, supporting their integration into compact and
energy-efficient continuous DAC modules. These findings establish pore
interconnectivity as a key design principle for next-generation solid
sorbents, enabling space-efficient, high-performance carbon removal
systems suitable for urban and distributed deployment. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFZekai Ji
Sanjeevi Jayakumar
Carlos Maria Alava Limpo
Aravind Madhav
Maxim Trubyanov
Pengxiang Zhang
Daria Andreeva V
Jong Hak Lee
Barbaros Ozyilmaz
- TI3D interconnected pore networks enable superior volumetric CO2
uptake in amine-functionalized nanoporous carbon for direct air
capture - SOCARBON CAPTURE SCIENCE & TECHNOLOGY
- DTArticle
- ABDirect Air Capture (DAC) is a critical technology for mitigating
atmospheric CO2 concentrations, but current systems require substantial
space and high energy input, largely due to the low volumetric CO2
capture capacity of existing sorbents. A major limitation arises from
the intrinsic trade-off in conventional mesoporous platforms, where
increasing amine loading often compromises CO2 diffusion efficiency,
resulting in poor volumetric performance. In this report, we introduce a
solid-state sorbent platform that overcomes this limitation by
leveraging a fully interconnected three-dimensional (3D) pore network.
The sorbent, composed of polyethyleneimine (PEI)-functionalized
nanoporous amorphous carbon (NAC) millimeter-sized monoliths, features a
hierarchically organized pore architecture with high volumetric pore
density, enabling deep and uniform amine infiltration while maintaining
unobstructed CO2 diffusion pathways. This synergistic pore design yields
a remarkable volumetric CO2 uptake of similar to 1.6 mmol/cm & sup3;
under pre-hydrated conditions-over threefold higher than that of the
best-performing shaped sorbents reported to date. The NAC-PEI monoliths
further exhibit cyclic stability, mechanical robustness, and negligible
pressure drop, supporting their integration into compact and
energy-efficient continuous DAC modules. These findings establish pore
interconnectivity as a key design principle for next-generation solid
sorbents, enabling space-efficient, high-performance carbon removal
systems suitable for urban and distributed deployment. - Z90
- PUELSEVIER
- PARADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS
- SN2772-6568
- VL19
- DI10.1016/j.ccst.2026.100600
- UTWOS:001724390300001
- ER
- EF
|
Zhang, Hongji; Grebenko, Artem K; Litvinov, Dmitrii; Zheng, Wenwen; Iakoubovskii, Konstantin V; Grebenchuk, Sergey Y; Makarova, Anna; Fedorov, Alexander; Starkov, Andrei; Orofeo, Carlo M; Vyalikh, Denis V; Lanza, Mario; Koperski, Maciej; Novoselov, Kostya S; Toh, Chee-tat; Ozyilmaz, Barbaros Breaking the 2-nm Barrier in Hard Disk Drives Using Monolayer Amorphous
Carbon Overcoats ADVANCED MATERIALS, 38 (15), 2026, DOI: 10.1002/adma.202519149. Abstract | BibTeX | Endnote @article{WOS:001680918000001,
title = {Breaking the 2-nm Barrier in Hard Disk Drives Using Monolayer Amorphous
Carbon Overcoats},
author = {Hongji Zhang and Artem K Grebenko and Dmitrii Litvinov and Wenwen Zheng and Konstantin V Iakoubovskii and Sergey Y Grebenchuk and Anna Makarova and Alexander Fedorov and Andrei Starkov and Carlo M Orofeo and Denis V Vyalikh and Mario Lanza and Maciej Koperski and Kostya S Novoselov and Chee-tat Toh and Barbaros Ozyilmaz},
doi = {10.1002/adma.202519149},
times_cited = {0},
issn = {0935-9648},
year = {2026},
date = {2026-03-01},
journal = {ADVANCED MATERIALS},
volume = {38},
number = {15},
publisher = {WILEY-V C H VERLAG GMBH},
address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
abstract = {The rapid growth of artificial intelligence (AI) has increased the
demand for large-scale data storage, making hard disk drives (HDDs)
indispensable in data centers due to their cost-effectiveness and
stability. To support AI-driven data requirements, increasing the areal
storage density is critical. However, this metric is increasingly
constrained by the carbon overcoat (COC), the essential protective layer
for magnetic media. Traditional diamond-like carbon (DLC) can no longer
fulfill the stringent demands for ultrathin coatings and high thermal
stability required by next-generation technologies like Heat-Assisted
Magnetic Recording (HAMR) and bit-patterned media. Here, we introduce
monolayer amorphous carbon (MAC) as a superior alternative. MAC is
directly grown on the heterogeneous (Fe, Pt, SiO2) HDD surface at low
temperatures (similar to 300 degrees C), achieving an uniform 0.8 nm
thickness across 2.5-inch disks. Despite its atomic thickness, MAC
demonstrates high corrosion resistance and low roughness comparable to
commercial 2.5 nm COCs. Its fully amorphous, sp2-hybridized structure
ensures excellent thermal stability under HAMR-like conditions (similar
to 450 degrees C) and a low friction coefficient, enabling potential
lubricant-free operation. Replacing traditional COCs with MAC
facilitates the development of HDD media capable of achieving 10 Tb/in2,
addressing the urgent storage demands of the digital era.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The rapid growth of artificial intelligence (AI) has increased the
demand for large-scale data storage, making hard disk drives (HDDs)
indispensable in data centers due to their cost-effectiveness and
stability. To support AI-driven data requirements, increasing the areal
storage density is critical. However, this metric is increasingly
constrained by the carbon overcoat (COC), the essential protective layer
for magnetic media. Traditional diamond-like carbon (DLC) can no longer
fulfill the stringent demands for ultrathin coatings and high thermal
stability required by next-generation technologies like Heat-Assisted
Magnetic Recording (HAMR) and bit-patterned media. Here, we introduce
monolayer amorphous carbon (MAC) as a superior alternative. MAC is
directly grown on the heterogeneous (Fe, Pt, SiO2) HDD surface at low
temperatures (similar to 300 degrees C), achieving an uniform 0.8 nm
thickness across 2.5-inch disks. Despite its atomic thickness, MAC
demonstrates high corrosion resistance and low roughness comparable to
commercial 2.5 nm COCs. Its fully amorphous, sp2-hybridized structure
ensures excellent thermal stability under HAMR-like conditions (similar
to 450 degrees C) and a low friction coefficient, enabling potential
lubricant-free operation. Replacing traditional COCs with MAC
facilitates the development of HDD media capable of achieving 10 Tb/in2,
addressing the urgent storage demands of the digital era. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFHongji Zhang
Artem K Grebenko
Dmitrii Litvinov
Wenwen Zheng
Konstantin V Iakoubovskii
Sergey Y Grebenchuk
Anna Makarova
Alexander Fedorov
Andrei Starkov
Carlo M Orofeo
Denis V Vyalikh
Mario Lanza
Maciej Koperski
Kostya S Novoselov
Chee-tat Toh
Barbaros Ozyilmaz
- TIBreaking the 2-nm Barrier in Hard Disk Drives Using Monolayer Amorphous
Carbon Overcoats - SOADVANCED MATERIALS
- DTArticle
- ABThe rapid growth of artificial intelligence (AI) has increased the
demand for large-scale data storage, making hard disk drives (HDDs)
indispensable in data centers due to their cost-effectiveness and
stability. To support AI-driven data requirements, increasing the areal
storage density is critical. However, this metric is increasingly
constrained by the carbon overcoat (COC), the essential protective layer
for magnetic media. Traditional diamond-like carbon (DLC) can no longer
fulfill the stringent demands for ultrathin coatings and high thermal
stability required by next-generation technologies like Heat-Assisted
Magnetic Recording (HAMR) and bit-patterned media. Here, we introduce
monolayer amorphous carbon (MAC) as a superior alternative. MAC is
directly grown on the heterogeneous (Fe, Pt, SiO2) HDD surface at low
temperatures (similar to 300 degrees C), achieving an uniform 0.8 nm
thickness across 2.5-inch disks. Despite its atomic thickness, MAC
demonstrates high corrosion resistance and low roughness comparable to
commercial 2.5 nm COCs. Its fully amorphous, sp2-hybridized structure
ensures excellent thermal stability under HAMR-like conditions (similar
to 450 degrees C) and a low friction coefficient, enabling potential
lubricant-free operation. Replacing traditional COCs with MAC
facilitates the development of HDD media capable of achieving 10 Tb/in2,
addressing the urgent storage demands of the digital era. - Z90
- PUWILEY-V C H VERLAG GMBH
- PAPOSTFACH 101161, 69451 WEINHEIM, GERMANY
- SN0935-9648
- VL38
- DI10.1002/adma.202519149
- UTWOS:001680918000001
- ER
- EF
|
Tewari, Chetna; Rawat, Kundan Singh; Kim, Youngnam; Arya, Tanuja; Dhali, Sunil; Rana, Sravendra; Andreeva, Daria V; Ozyilmaz, Barbaros; Mahfouz, Remi; Qari, Nada; Jung, Yong Chae; Sahoo, Nanda Gopal; Novoselov, Kostya S Functional nanocarbons from waste plastics for energy storage
applications RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 226 (E), 2026, DOI: 10.1016/j.rser.2025.116443. Abstract | BibTeX | Endnote @article{WOS:001614303300001,
title = {Functional nanocarbons from waste plastics for energy storage
applications},
author = {Chetna Tewari and Kundan Singh Rawat and Youngnam Kim and Tanuja Arya and Sunil Dhali and Sravendra Rana and Daria V Andreeva and Barbaros Ozyilmaz and Remi Mahfouz and Nada Qari and Yong Chae Jung and Nanda Gopal Sahoo and Kostya S Novoselov},
doi = {10.1016/j.rser.2025.116443},
times_cited = {9},
issn = {1364-0321},
year = {2026},
date = {2026-01-01},
journal = {RENEWABLE & SUSTAINABLE ENERGY REVIEWS},
volume = {226},
number = {E},
publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
abstract = {The mismanagement of waste plastic could lead to significant
environmental challenge, underscoring the urgent need for adopting
innovative strategies that will address its management and utilization.
At the same time, the growing demand for sustainable energy storage
materials necessitates the exploration of resourceful solutions
including advanced plastic-based materials. Addressing these dual
concerns, this review examines the transformation of waste plastics into
functional nanocarbons (FNCs) for energy-related applications. This
review provides a comprehensive analysis of zero-to-three-dimensional
FNCs derived from waste plastics, detailing synthesis techniques such as
chemical vapor deposition, pyrolysis/catalytic pyrolysis, and
hydrothermal carbonization, along with the underlying mechanisms. Key
factors influencing the conversion process-including pressure,
temperature, and catalytic systems-are thoroughly examined. Discussions
on morphology and surface chemistry shed light on strategies to optimize
material properties for specific applications. Special attention is
given to the performance of FNCs in supercapacitors and batteries, using
benchmarks such as electrical conductivity, specific surface area, and
cycling stability to evaluate their suitability for energy storage.
Additionally, the review incorporates a circular economic perspective,
offering insights into how upcycling waste plastics into FNCs can
contribute to a more sustainable future. It identifies critical research
gaps, evaluates the environmental impacts of these processes, and
highlights promising opportunities for innovation. By fostering
interdisciplinary collaboration and bridging knowledge gaps, this review
aims to inspire advancements in both waste plastic upcycling and energy
technologies, ultimately contributing to sustainable solutions for
urgent environmental and energy challenges.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The mismanagement of waste plastic could lead to significant
environmental challenge, underscoring the urgent need for adopting
innovative strategies that will address its management and utilization.
At the same time, the growing demand for sustainable energy storage
materials necessitates the exploration of resourceful solutions
including advanced plastic-based materials. Addressing these dual
concerns, this review examines the transformation of waste plastics into
functional nanocarbons (FNCs) for energy-related applications. This
review provides a comprehensive analysis of zero-to-three-dimensional
FNCs derived from waste plastics, detailing synthesis techniques such as
chemical vapor deposition, pyrolysis/catalytic pyrolysis, and
hydrothermal carbonization, along with the underlying mechanisms. Key
factors influencing the conversion process-including pressure,
temperature, and catalytic systems-are thoroughly examined. Discussions
on morphology and surface chemistry shed light on strategies to optimize
material properties for specific applications. Special attention is
given to the performance of FNCs in supercapacitors and batteries, using
benchmarks such as electrical conductivity, specific surface area, and
cycling stability to evaluate their suitability for energy storage.
Additionally, the review incorporates a circular economic perspective,
offering insights into how upcycling waste plastics into FNCs can
contribute to a more sustainable future. It identifies critical research
gaps, evaluates the environmental impacts of these processes, and
highlights promising opportunities for innovation. By fostering
interdisciplinary collaboration and bridging knowledge gaps, this review
aims to inspire advancements in both waste plastic upcycling and energy
technologies, ultimately contributing to sustainable solutions for
urgent environmental and energy challenges. - FNClarivate Analytics Web of Science
- VR1.0
- PTJ
- AFChetna Tewari
Kundan Singh Rawat
Youngnam Kim
Tanuja Arya
Sunil Dhali
Sravendra Rana
Daria V Andreeva
Barbaros Ozyilmaz
Remi Mahfouz
Nada Qari
Yong Chae Jung
Nanda Gopal Sahoo
Kostya S Novoselov
- TIFunctional nanocarbons from waste plastics for energy storage
applications - SORENEWABLE & SUSTAINABLE ENERGY REVIEWS
- DTArticle
- ABThe mismanagement of waste plastic could lead to significant
environmental challenge, underscoring the urgent need for adopting
innovative strategies that will address its management and utilization.
At the same time, the growing demand for sustainable energy storage
materials necessitates the exploration of resourceful solutions
including advanced plastic-based materials. Addressing these dual
concerns, this review examines the transformation of waste plastics into
functional nanocarbons (FNCs) for energy-related applications. This
review provides a comprehensive analysis of zero-to-three-dimensional
FNCs derived from waste plastics, detailing synthesis techniques such as
chemical vapor deposition, pyrolysis/catalytic pyrolysis, and
hydrothermal carbonization, along with the underlying mechanisms. Key
factors influencing the conversion process-including pressure,
temperature, and catalytic systems-are thoroughly examined. Discussions
on morphology and surface chemistry shed light on strategies to optimize
material properties for specific applications. Special attention is
given to the performance of FNCs in supercapacitors and batteries, using
benchmarks such as electrical conductivity, specific surface area, and
cycling stability to evaluate their suitability for energy storage.
Additionally, the review incorporates a circular economic perspective,
offering insights into how upcycling waste plastics into FNCs can
contribute to a more sustainable future. It identifies critical research
gaps, evaluates the environmental impacts of these processes, and
highlights promising opportunities for innovation. By fostering
interdisciplinary collaboration and bridging knowledge gaps, this review
aims to inspire advancements in both waste plastic upcycling and energy
technologies, ultimately contributing to sustainable solutions for
urgent environmental and energy challenges. - Z99
- PUPERGAMON-ELSEVIER SCIENCE LTD
- PATHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
- SN1364-0321
- VL226
- DI10.1016/j.rser.2025.116443
- UTWOS:001614303300001
- ER
- EF
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